帮助 关于我们

返回检索结果

木质素催化解聚的研究进展
Progress in catalytic depolymerization of lignin

查看参考文献68篇

文摘 木质素是一种芳环结构来源丰富且价格低廉的可再生资源。从木质素出发催化解聚制备单酚类高附加值精细化学品和芳香烃烷烃等高品位生物燃料,可以部分替代以化石燃料为原料的生产过程,是生物质资源全组分高效综合利用的重要组成部分。在木质素催化解聚方法中,催化氢解可以直接将木质素转化为低氧含量的液体燃料,在生物燃料利用方面展现出巨大的潜力。本文详细总结了木质素的催化解聚方法,从催化剂类型、溶剂种类、反应机理及催化剂循环使用性等方面介绍了国内外的主要研究进展,着重阐述了木质素催化氢解方法。最后总结了当前木质素催化解聚过程中存在的难题,并对未来的技术发展提出了建议和展望。
其他语种文摘 Lignin is a cheap and renewable resource with rich aromatic units. It can be efficiently transformed into highly value-added fine chemicals such as phenolic monomers and other high-grade biofuels such as arenes and alkanes through catalytic depolymerization methods, which has long been regarded as an important constituent part of biomass resources comprehensive utilization approaches. This process is able to replace the chemicals production from the fossil fuel partly. Among the lignin depolymerization methods, the catalytic hydrogenolysis process can directly convert lignin into liquid fuel with low oxygen contents, and these biofuels show a great potential in the replacement of traditional energy sources. This paper focuses on the catalytic lignin depolymerization methods. The recent progress at home and abroad is reviewed based on the catalysts, solvents, catalysis mechanism and catalyst recyclability. Wherein, the catalytic hydrogenolysis method is emphatically introduced in detail. Furthermore, the current technique challenges during the lignin catalytic depolymerization process are summarized. Many future technologic explorations and suggestions for the efficient application of lignin are proposed.
来源 化工学报 ,2016,67(11):4523-4532 【核心库】
DOI 10.11949/j.issn.0438-1157.20160885
关键词 生物质 ; 木质素 ; 催化 ; 降解 ; 生物燃料
地址

中国科学院广州能源研究所, 中国科学院可再生能源重点实验室;;广东省新能源和可再生能源研究开发与应用重点实验室, 广东, 广州, 510640

语种 中文
文献类型 综述型
ISSN 0438-1157
学科 能源与动力工程
基金 国家自然科学基金项目 ;  国家科技支撑计划项目
文献收藏号 CSCD:5842648

参考文献 共 68 共4页

1.  Zakzeski J. The catalytic valorization of lignin for the production of renewable chemicals. Chem. Rev,2010,110:3552-3599 被引 181    
2.  孔劼琛. 木质素解聚和加氢脱氧的进展. 中国科学: 化学,2015,45(5):510-525 被引 8    
3.  路瑶. 木质素的结构研究与应用. 化学进展,2013,25:839-858 被引 1    
4.  Li C. Catalytic transformation of lignin for the production of chemicals and fuels. Chem. Rev,2015,115(21):11559-11624 被引 68    
5.  Kubo S. Hydrogen bonding in lignin: a Fourier transform infrared model compound study. Biomacromolecules,2005,6:2815-2821 被引 10    
6.  Brunow G. Biorefineries-Industrial Processes and Products,2006:151 被引 2    
7.  郭京波. 竹木质素的红外光谱与X射线光电子能谱分析. 化学学报,2005,63(16):1536-1540 被引 9    
8.  Yaghoubi K. Variable optimization for biopulping of agricultural residues by Ceriporiopsis subvermispora. Bioresour. Technol,2008,99(10):4321-4328 被引 13    
9.  Li S H. A sustainable approach for lignin valorization by heterogeneous photocatalysis. Green Chem,2016,18:594-607 被引 12    
10.  Crestini C. Singlet oxygen in the photodegradation of lignin models. Tetrahedron,1997,53(23):7877-7888 被引 7    
11.  陈磊. 木质素结构及热解特性. 化工学报,2014,65(9):3626-3633 被引 19    
12.  程辉. 木质素慢速热解机理. 化工学报,2013,64(5):1757-1765 被引 33    
13.  武书彬. 工业碱木素热裂解特性研究. 北京林业大学学报,2008,30(5):143-147 被引 11    
14.  Nair V. Production of guaiacols via catalytic fast pyrolysis of alkali lignin using titania, zirconia and ceria. J. Anal. Appl. Pyrol,2016,119:31-39 被引 6    
15.  Custodis V B. Catalytic fast pyrolysis of lignin over high-surface-area mesoporous aluminosilicates: effect of porosity and acidity. ChemSusChem,2016,9:1134-1145 被引 6    
16.  Amen-Chen C. Production of monomeric phenols by thermochemical conversion of biomass. Bioresour. Technol,2001,79:277-299 被引 44    
17.  Schuchardt U. Liquefaction of hydrolytic eucalyptus lignin with formate in water, using batch and continuous-flow reactors. Bioresour. Technol,1993,44(2):123-129 被引 6    
18.  Mullen C A. Catalytic pyrolysis-GC/MS of lignin from several sources. Fuel Process. Technol,2010,91:1446-1458 被引 23    
19.  Shafizadeh F. Thermal deterioration of wood. Wood Technol.: Chem. Aspects, Symposium, 43,1976:57-81 被引 1    
20.  Serio M E. Production of carbon materials from biomass. Division Fuel Chem,1991,36:1110-1118 被引 1    
引证文献 8

1 刘新鑫 酸性体系V催化木质素β-O-4模型物C-C键高选择性切断 化学学报,2017,75(8):788-793
被引 2

2 刘长军 NHPI催化分子氧选择性氧化木质素模型分子中的C—C键 化工学报,2017,68(10):3788-3794
被引 0 次

显示所有8篇文献

论文科学数据集
PlumX Metrics
相关文献

 作者相关
 关键词相关
 参考文献相关

版权所有 ©2008 中国科学院文献情报中心 制作维护:中国科学院文献情报中心
地址:北京中关村北四环西路33号 邮政编码:100190 联系电话:(010)82627496 E-mail:cscd@mail.las.ac.cn 京ICP备05002861号-4 | 京公网安备11010802043238号