拉曼光谱表征石墨烯结构的研究进展
Research Progress on Characterization of Graphene Structure by Raman Spectroscopy
查看参考文献71篇
|
文摘
|
石墨烯是一种只有一个原子层的二维原子晶体,它是构成零维富勒烯、一维碳纳米管和三维石墨等其他碳同素异形体的基本结构单元,具有很多独特的电子及力学性能,因而吸引了化学、材料及其他领域众多科学家的高度关注。拉曼光谱作为一种灵敏便捷的表征方法,在石墨烯的研究中起到重要的作用。该综述总结了近年来拉曼光谱在石墨烯表征中的应用,在对单层石墨烯的典型特征峰作详细介绍的基础上,通过对拉曼谱图中D峰、G峰和2D峰的强度、位置和半峰宽变化情况的分析,可以快速而准确地表征出石墨烯的层数,并可以对石墨烯的堆垛方式、边缘手性和掺杂程度进行判定。同时,也系统地分析了在石墨烯制备与测试过程中基底、掺杂、温度和激光功率等因素对拉曼谱图中D峰、G峰和2D峰的强度、位置和半峰宽的影响。 |
|
其他语种文摘
|
Graphene is a kind of two-dimensional atomic crystal with one atomic layer,which is the basic structure unit of other dimensions of graphite materials,such as zero dimensional fullerenes, one-dimensional carbon nanotubes and three-dimensional graphite.Graphene has a lot of unique electronic and mechanical properties,which have attracted high attention of many scientists in the field of chemistry,materials and other fields.Raman spectroscopy as a sensitive and convenient characterization method,has played a very important role in the study of graphene.Raman spectroscopy is an integral part of graphene research.The application of Raman spectroscopy in graphene characterization in recent years is reviewed in this paper.The characteristic peak of monolayer graphene was first intnduced. Then,through the analysis of the changes of D peak,G peak and 2Dpeak intensity,position and half peak width of Raman spectra,the number of graphene layers can be quickly and accurately characterized,as well as,the stacking orders,edge chirality and doping degree of graphene were defined. At the same time,the effects of substrate,doping,temperature and laser power on the intensity, position and half width of D peak,G peak and 2Dpeak of Raman spectra in the process of preparing graphene were also systematically analyzed. |
|
来源
|
材料工程
,2018,46(5):1-10 【核心库】
|
|
DOI
|
10.11868/j.issn.1001-4381.2016.001341
|
|
关键词
|
石墨烯
;
拉曼光谱
;
层数效应
;
堆垛方式
;
边缘手性
;
掺杂程度
|
|
地址
|
1.
北京工业大学材料科学与工程学院, 北京, 100124
2.
中国标准化研究院, 北京, 100142
|
|
语种
|
中文 |
|
文献类型
|
综述型 |
|
ISSN
|
1001-4381 |
|
学科
|
化学 |
|
基金
|
北京市科技计划项目
;
北京市教委科研基金
;
中国标准化研究院院长基金项目
|
|
文献收藏号
|
CSCD:6245026
|
参考文献 共
71
共4页
|
|
1.
Wallace P R. The band theory of graphite.
Physical Review,1947,71(9):622-634
|
CSCD被引
106
次
|
|
|
|
|
2.
Mcclure J W. Diamagnetism of graphite.
Physical Review,1956,104(3):666-671
|
CSCD被引
11
次
|
|
|
|
|
3.
Novoselov K S. Electric field effect in atomically thin carbon films.
Science,2004,306(5696):666-669
|
CSCD被引
4039
次
|
|
|
|
|
4.
Meyer J C. The structure of suspended graphene sheets.
Nature,2007,446(7131):60-63
|
CSCD被引
303
次
|
|
|
|
|
5.
Geim A K. The rise of graphene.
Nature Materials,2007,6(3):183-191
|
CSCD被引
2266
次
|
|
|
|
|
6.
Shin D. Synthesis and applications of graphene electrodes.
Carbon Letters,2012,13(1):1-16
|
CSCD被引
4
次
|
|
|
|
|
7.
Zhang Y B. Experimental observation of quantum hall effect and Berry's phase in graphene.
Nature,2005,438(7065):1-7
|
CSCD被引
1
次
|
|
|
|
|
8.
Yang H. Graphene barrister,a triode device with a gate-controlled Schottky barrier.
Science,2012,336(6085):1140-1143
|
CSCD被引
33
次
|
|
|
|
|
9.
Lu J M. Graphene magnetoresistance device in van der Pauw geometry.
Nano Letters,2011,11(7):2973-2977
|
CSCD被引
2
次
|
|
|
|
|
10.
Zhu Y. Rational design of hybrid graphene films for high-performance transparent electrodes.
Acs Nano,2011,5(8):6472-6479
|
CSCD被引
7
次
|
|
|
|
|
11.
Arco L G D. Continuous, highly flexible,and transparent graphene films by chemical vapor deposition for organic photovoltaics.
Acs Nano,2010,4(5):2865-2873
|
CSCD被引
4
次
|
|
|
|
|
12.
Wu C H. Preparation of novel three-dimensional NiO/ultrathin derived graphene hybrid for supercapacitor applications.
ACS Applied Materials &Interfaces,2014,6(2):1106-1112
|
CSCD被引
10
次
|
|
|
|
|
13.
Wu C H. Three-dimensional Co_3O_4/flocculent graphene hybrid on Ni foam for supercapacitor applications.
Journal of Materials Chemistry A,2014,2(38):15987-15994
|
CSCD被引
1
次
|
|
|
|
|
14.
Ferrari A C. Raman spectrum of graphene and graphene layers.
Physical Review Letters,2006,97(18):13831-13840
|
CSCD被引
476
次
|
|
|
|
|
15.
Kuzmany H. Raman spectroscopy of fullerenes and fullerene-nanotube composites.
Philosophical Transactions of the Royal Society A Mathematical Physical & Engineering Sciences,2004,362(1824):2375-2406
|
CSCD被引
5
次
|
|
|
|
|
16.
Dresselhaus M S. Raman spectroscopy on isolated single wall carbon nanotubes.
Carbon,2002,40(12):2043-2061
|
CSCD被引
37
次
|
|
|
|
|
17.
Ferrari A C. Resonant Raman spectroscopy of disordered,amorphous,and diamondlike carbon.
Physical Review B Condensed Matter,2001,64(7):075414-1-075414-13
|
CSCD被引
107
次
|
|
|
|
|
18.
Mi R. Effects of nitrogen-doped carbon nanotubes on the discharge performance of Li-air batteries.
Carbon,2014,67(2):744-752
|
CSCD被引
8
次
|
|
|
|
|
19.
Ferrari A C. Raman spectroscopy as a versatile tool for studying the properties of graphene.
Nature Nanotechnology,2013,8(4):235-246
|
CSCD被引
213
次
|
|
|
|
|
20.
Malard L M. Probing the electronic structure of bilayer graphene by Raman scattering.
Physical Review B Condensed Matter,2007,76(20):1401-1-1401-4
|
CSCD被引
7
次
|
|
|
|
|
了解气象卫星更多信息，请访问