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基于MOFs的碳纳米管复合材料的制备和应用进展
Progress in preparation and application of carbon nanotube composites based on MOFs

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文摘 碳纳米管(CNTs)作为纳米材料研究中的一个重要发现,自其诞生以来就成为碳材料领域的研究热点之一。金属有机框架(MOFs)凭借其独特的多孔结构,近年来在各领域的应用已经成为研究前沿之一。随着材料科学的不断发展,对具有不同功能特性材料的复合技术研究,已经成为解决材料应用领域中关键问题的主要方法。而碳纳米管和金属有机框架作为目前材料领域两类十分重要的纳米材料,通过复合技术将碳纳米管的高导电特性和金属有机框架材料的高比表面积、丰富孔道分布特性相结合是研究与应用的必然趋势。本文综述了近年来金属有机框架和碳纳米管的主要复合形式和制备方法,整理了复合材料在超级电容器、锂电池、催化、吸附等领域的最新研究进展,对两种材料性能的协同提升方面进行了讨论和总结,并指出CNTs与MOFs材料的复合以及CNTs的生长分布具有很高的随机性,对其实现进一步控制是未来的技术研究重点。
其他语种文摘 Carbon nanotubes(CNTs),as an important discovery in the research of nanomaterials,have become a research hotspot in the field of carbon materials since their birth.With its unique porous structure,metal-organic frameworks(MOFs)has been developed into one of the frontiers of research in recent years.With the continuous development of materials science in recent years,the research on composite technology of materials with different functional characteristics has become one of the main methods to solve key problems in the field of materials applications.CNTs and MOFs are two very important types of nanomaterials in the current material field.Combining the high electrical conductivity of CNTs with the high specific surface area and rich pore distribution characteristics of MOFs through composite technology is an inevitable trend for future research and application in the field of materials.In this paper,the main composite forms and preparation methods of MOFs and CNTs in recent years were reviewed,and the latest research progress of composites in the fields of supercapacitors,lithium battery electrodes,catalysis,adsorption,etc.was summarized.The synergistic improvement of the performance of the two materials was discussed and analyzed,and it was pointed out that the composite of CNTs and MOFs materials and the growth and distribution of CNTs have a high degree of randomness,and further control of them is the focus of future technical research.
来源 材料工程 ,2021,49(9):27-40 【核心库】
DOI 10.11868/j.issn.1001-4381.2020.000599
关键词 碳纳米管 ; 金属有机框架 ; 复合材料 ; 原位生长
地址

中国民航大学民航热灾害防控与应急重点实验室, 天津, 300300

语种 中文
文献类型 综述型
ISSN 1001-4381
学科 化学
基金 中国民航大学科研启动费项目
文献收藏号 CSCD:7073073

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