市政垃圾焚烧炉烟道气中氯代和溴代二恶英分布
DISTRIBUTION CHARACTERISTIC OF PCDD/Fs AND PBDD/Fs IN FLUE GAS FROM MUNICIPAL SOLID WASTE INCINERATORS
查看参考文献19篇
|
文摘
|
为了探明固废焚烧炉烟道气中PCDD/Fs 和PBDD/Fs 的浓度、分布特征和二者之间的相关性,用气相色谱/高分辨质谱测定2,3,7,8位氯代和溴代二恶英(PCDD/Fs 和PBDD/Fs) 。两者的总毒性当量浓度在A 厂分别为0.043 ~ 1.20,0.00056 ~ 0.010 ng I-TEQ/m~3,在B 厂分别为0.024 ~ 0.069,0.0034 ~ 0.0043 ng I-TEQ/m~3。A 厂的PCDD/Fs 以PCDFs 为主,B 厂相对浓度最大的是OCDD。影响PCDD/Fs 的浓度和分布可能主要为垃圾含氯量和空气净化设施。 PBDD/Fs 都主要含PBDFs。两厂的PCDD/Fs 和PBDD/Fs 浓度具有较好的相关性。 |
|
其他语种文摘
|
To investigate the concentrations,congener profiles and relationship of 2,3,7,8-substituted polychlorinated dibenzo-p-dioxins and polychlorinated furans (PCDD/Fs),and polybrominated dibenzo-p-dioxins and polybrominated furans (PBDD/Fs) in the stack flue gases from municipal solid waste incinerations (MSWIs),gas chromatograph coupled with high resolution mass spectrometry was applied. The TEQ concentrations of PCDD/Fs and PBDD/Fs respectively ranged in 0.043 ~ 1.0,0.00056 ~ 0.010 ng I-TEQ/m~3 in plant A,and in 0.024 ~ 0.069,0.0034 ~ 0.0043 ng I-TEQ/m~3 in plant B. The congener profiles of PCDD/Fs in the stack flue gases were dominated by PCDFs in plant A,while by OCDD in plant B. The concentrations and congener profiles of PCDD/Fs in the stack flues gases were probably mostly affected by the chlorine contents in feeding wastes and the air pollution control devices. For PBDD/Fs,PBDFs were abundant in all flue gas samples of plant A and B. There were good correlations between the concentrations of PCDD/Fs and PBDD/Fs. |
|
来源
|
环境工程
,2015,33(11):78-82,141 【扩展库】
|
|
DOI
|
10.13205/j.hjgc.201511016
|
|
关键词
|
焚烧炉
;
烟道气
;
PCDD/Fs
;
PBDD/Fs
;
相关性
|
|
地址
|
中国科学院广州地球化学研究所, 有机地球化学国家重点实验室, 广州, 510640
|
|
语种
|
中文 |
|
文献类型
|
研究性论文 |
|
ISSN
|
1000-8942 |
|
基金
|
国家自然科学基金
;
广东省自然科学基金
|
|
文献收藏号
|
CSCD:5580210
|
参考文献 共
19
共1页
|
|
1.
中华人民共和国环境保护部.
2012年环境统计年报,2012
|
被引
2
次
|
|
|
|
|
2.
国务院办公厅.
"十二五"全国城镇生活垃圾无害化处理设施建设规划,2012
|
被引
3
次
|
|
|
|
|
3.
Wei Y M. Mineralogical characterization of municipal solid waste incineration bottom ash with an emphasis on heavy metal-bearing phase.
Journal of Hazardous Materials,2011,187(1/3):534-543
|
被引
9
次
|
|
|
|
|
4.
Olie K. Chlorodibenzo-p-dioxins and chlorodibenzofurans are trace components of fly ash and flue gas of some municipal incinerators in the Netherlands.
Chemosphere,1977,6(8):455-459
|
被引
47
次
|
|
|
|
|
5.
.
HJ 77.2-2008《环境空气和废气二恶英类的测定同位素稀释高分辨气相色谱-高分辨气相质谱法》
|
被引
1
次
|
|
|
|
|
6.
U S. Environmental Protection Agency.
Tetra-through octachlorinated dioxins and furans by isotope dilution HRGC/HRMS (Method 1613),1994
|
被引
1
次
|
|
|
|
|
7.
李荟茹. 大气样品中氯代和溴代二恶英/呋喃同位素稀释分析方法的建立及应用.
分析化学,2008,36(2):150-156
|
被引
1
次
|
|
|
|
|
8.
Wang L C. Characterizing the emissions of polybrominated dibenzo-p-dioxins and dibenzofurans from municipal and industrial waste incinerators.
Environment Science and Technology,2007,41(4):1159-1165
|
被引
5
次
|
|
|
|
|
9.
Wang M S. Characterization of Persistent Organic Pollutants Emitted from a Municipal Solid Waste Incinerator in Taiwan.
Environmental Engineering Science,2010,27(11):955-965
|
被引
2
次
|
|
|
|
|
10.
Wang L C. Distribution of polybrominated diphenyl ethers (PBDEs) and polybrominated dibenzo-p-dioxins and dibenzofurans (PBDD/Fs) in municipal solid waste incinerators.
Environmental Pollution,2010,158(5):1595-1602
|
被引
14
次
|
|
|
|
|
11.
Zhang G. Characterization and mass balance of dioxin from a large-scale municipal solid waste incinerator in China.
Waste Management,2012,32(6):1156-1162
|
被引
19
次
|
|
|
|
|
12.
Chang M B. Measurement of PCDD/ F congener distributions in MWI stack gas and ambient air in northern Taiwan.
Atmospheric Environment,2004,38(16):2535-2544
|
被引
5
次
|
|
|
|
|
13.
杨志军. 不同垃圾焚烧炉产生的PCDD/Fs和PCBs同类物的分布.
环境化学,2005,24(1):63-67
|
被引
10
次
|
|
|
|
|
14.
黄文. 医疗废物焚烧炉周边环境介质中二英的浓度、 同系物分布与来源分析.
环境科学,2013,34(8):3238-3243
|
被引
10
次
|
|
|
|
|
15.
Wang L C. Effect of chlorine content in feeding wastes of incineration on the emission of polychlorinated dibenzo-p-dioxins /dibenzofurans.
The Science of the Total Environment,2003,302(1/3):185-198
|
被引
12
次
|
|
|
|
|
16.
Yasuhara A. Formation of dioxins during the combustion of newspapers in the presence of sodium chloride and poly(vinyl chloride).
Environment Science and Technology,2001,35(7):1373-1378
|
被引
8
次
|
|
|
|
|
17.
Hatanaka T. Formation of PCDD/Fs in artificial solid waste incineration in a laboratory-scale fluidized-bed reactor:influence of contents and forms of chlorine sources in hightemperature combustion.
Environment Science and Technology,2000,34(18):3920-3924
|
被引
6
次
|
|
|
|
|
18.
Randall D.
An evaluation of the cost of incinerating wastes containing PVC, 31,1994:1-17
|
被引
1
次
|
|
|
|
|
19.
Wegiel M. Study on the impact of industrial flue gases on the PCDD/Fs congener profile in ambient air.
Chemosphere,2014,114:76-83
|
被引
1
次
|
|
|
|
|
了解气象卫星更多信息，请访问