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表面纳米化预自理对低碳钢气体渗氮行为的影响
Effects of Surface Nanocrystallization Pre-treatment on Gas Nitriding Behavior of Mild Steel

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卑多慧 1   吕坚 2   顾剑锋 1   卢柯 3   潘健生 1  
文摘 研究了表面喷丸纳米化预处理对气体渗氮行为的影响。利用低碳钢试样单面表面超声喷丸纳米化处理,另一面保持原始晶粒,在460 ℃、500 ℃、560 ℃、640 ℃四种温度不同时间气体渗氮,通过金相观察和X射线衍射法测定渗氮层的厚度和种类。对比发现在560 ℃以下渗氮时,经过表面喷丸纳米化预处理:可以提高扩散系数D和气-固传递系数β,降低氮势门槛值;使常规渗氮温度降低50 ℃左右或者渗氮时间缩短50%;使渗氮层厚度随渗氮时间增长在初期就符合抛物线规律x = At~(0.5)。640 ℃短时间渗氮时,表面纳米化预处理仍然可以起到一定的加速作用,但是随着渗氮时间的延长,表面纳米化预处理优势消失,甚至会阻碍渗层厚度的增长。
其他语种文摘 The effects of surface ultrasonic shot peening (SUSSP) nanocrystallization on gas nitriding were studied. The mild steel plates were SUSSP nanocrystallized on one side but the original coarse-grained condition on the opposite side. The relationship between the compound layer growth and nitriding time for two types of surface condition was obtained by gas nitriding at 460 ℃, 500 ℃, 560 ℃, 640 ℃ respectively with different nitriding times. The thickness of compound layer was determined by metallographic observation and the phases appeared on the top surface were identified by x-ray diffraction. When gas nitriding below 560 ℃, SUSSP nanocrystallization treatment could not only enhance both diffusion coefficient D and mass transfer coefficient β dramatically during the gaseous nitriding process but also reduce the threshold nitriding potential. With SUSSP pre-treatment, the nitriding rate can be accelerated so dramatically that nitriding time can be reduced to the half, or the conventional nitriding temperature could be reduced approximately 50 ℃. The growth of compound layer with nitriding time assumed parabolic relationship from the start of nitriding process as long as the sample surface was pre-treated by SUSSP. In the case of gaseous nitriding at 640 ℃, SUSSP pretreatment is still of some advantages to accelerating nitriding rate when nitriding time is shorter than 3 hours. With the further progress of nitriding, the advantage of SUSSP pretreatment wiel disappears and even on the contrary might slow nitride growth.
来源 材料热处理学报 ,2002,23(1):19-24 【核心库】
关键词 超声喷丸表面纳米化 ; 气体渗氮 ; 生长动力学
地址

1. 上海交通大学材料科学与工程学院, 上海, 200030  

2. LASMIS, University of Technology of Troyes, Troyes, 10000  

3. 中国科学院金属研究所, 快速凝固非平衡合金国家重点实验室, 沈阳, 110015

语种 中文
文献类型 研究性论文
ISSN 1009-6264
学科 金属学与金属工艺
文献收藏号 CSCD:959725

参考文献 共 11 共1页

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引证文献 36

1 熊天英 超音速微粒轰击金属表面纳米化新技术 材料导报,2003,17(3):69-71
被引 41

2 高玉魁 表面形变处理对32Cr3MoVA钢渗氮层组织和性能的影响 材料热处理学报,2005,26(1):74-76
被引 12

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