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航空发动机用聚酰亚胺树脂基复合材料固化工艺及热稳定性能
Curing process and thermal stability of polyimidematrix composite for aero-engines

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倪洪江 1,2 *   邢宇 1,2   戴霄翔 1,2   李军 1,2   张代军 1,2   陈祥宝 1,2 *  
文摘 针对航空发动机的需求,开展聚酰亚胺树脂基结构复合材料固化工艺与热稳定性评价研究。建立EC-380A树脂的固化动力学方程,模拟树脂固化度随温度和时间的变化。进一步结合树脂流变特性,制定并验证EC-380A复合材料固化成型工艺,制备发动机大尺寸复合材料典型件。通过热老化失重、预置缺陷层合板内部质量和力学性能,评价复合材料的热稳定性。采用330~380℃多温度分级固化的方法,复合材料可整体铺贴无缺陷热压成型。复合材料热稳定性优异,具备370~400℃耐温能力,370℃和285℃累计热老化1000 h,复合材料失重在1.3%左右;400℃热老化后,复合材料无新增缺陷、预置缺陷无扩展,表现出高温结构稳定性。
其他语种文摘 Aiming at the need of aero-engines,investigation was made into the curing process and thermal stability of a polyimide-matrix structural composite.The curing kinetic equation of EC-380A resin was established.The curing degree of the resin was simulated as a function of the curing temperature and time.Further,combined with the resin rheology,the curing process of the EC-380A composite was established and verified.Large-scaled aero-engine typical structural components were fabricated.Thermal stability of the composite was estimated by mass loss,internal quality of the flaw-embedded laminate,and mechanical property after thermal ageing.By multi-temperature step curing at 330-380 ℃,the flaw-free composite could be manufactured under the circumstance of an integrated layup.The composite has excellent thermal stability with thermal resistance of 370-400℃. The mass loss rate is around 1.3% after ageing for 1000 hat 370 ℃ and 285℃.No new flaw or propagation of the embedded flaw occurs for the composite after thermal ageing at 400℃,indicating a high-temperature structural stability.
来源 材料工程 ,2022,50(7):102-109 【核心库】
DOI 10.11868/j.issn.1001-4381.2021.001238
关键词 航空发动机复合材料 ; 聚酰亚胺 ; 固化工艺 ; 热稳定性 ; 预置缺陷
地址

1. 中国航发北京航空材料研究院软材料技术研究中心, 北京  

2. 先进复合材料国防科技重点实验室, 先进复合材料国防科技重点实验室, 北京

语种 中文
文献类型 研究性论文
ISSN 1001-4381
学科 航空
基金 中国科协青年人才托举工程项目 ;  国家重大科技专项
文献收藏号 CSCD:7261529

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引证文献 3

1 万宝全 动态可持续聚酰亚胺电介质材料应用与进展 工程科学与技术,2023,55(3):30-39
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2 付善龙 航空用国产碳纤维/聚酰亚胺复合材料耐环境老化性能 热固性树脂,2023,38(4):1-6
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