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人造板废弃物烘焙热解特性研究
RESEARCH ON TORREFACTION PYROLYSIS CHARACTERISTICS OF WOOD-BASED PANELWASTE

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王南涛 1,2   詹昊 3   庄修政 1,2   宋艳培 1,2   阴秀丽 1   吴创之 1,2 *  
文摘 以具有代表性的两类人造板废弃物--胶合板(PW)和纤维板(FB)为原料开展烘焙实验,结合元素、热值、傅里叶红外(FTIR)、二维相关红外(2D-PCIS)、X射线光电子能谱(XPS)等分析表征手段,探究烘焙预处理对人造板废弃物化学结构及其燃料品质的影响。结果表明,在200 ℃和250 ℃下,PW和FB烘焙固体产物化学结构变化并不明显,但在300 ℃下,发生明显变化。随着烘焙温度的升高,人造板废弃物中低能态的“-C-H/-C-O/-C==O”键向高能态的“芳香族-C-C/-C==C”键转变,燃料热值显著提高,并在300 ℃下,PW和FB获得最大脱氮效率,分别为75.04%和72.48%。
其他语种文摘 The torrefaction experiments were carried out using two typical wood- based panel wastes:Plywood(PW)and Fiberboard (FB). The influences of torrefaction on chemical structure and fuel property of wood- based panel wastes were researched using the analytical characterization by combining with the element,calorific value,Fourier transform infrared spectroscopy(FTIR),twodimensional correlation infrared spectroscopy(2D- PCIS)and X- ray photoelectron spectroscopy(XPS). The results show that the chemical structure of PW and FB do not change a lot at 200 ℃ even at 250 ℃,but at 300 ℃,significant changes will occur. With the increase of torrefaction temperature,the low- energy states of“ -C-H/-C-O/-C==O”change into the high- energy states of “aromatic -C-C/-C==C”,and the calorific value of torrefied solid increases significantly. Simultaneously,at 300 ℃,PW and FB obtain the maximum denitrogenation rate,which is 75.04 % and 72.48 %,respectively.
来源 太阳能学报 ,2021,42(12):283-291 【扩展库】
DOI 10.19912/j.0254-0096.tynxb.2019-1104
关键词 生物质废弃物 ; 烘焙 ; 化学结构 ; 预处理
地址

1. 中国科学院广州能源研究所, 中国科学院可再生能源重点实验室;;广东省新能源和可再生能源研究开发与应用重点实验室, 广州, 510640  

2. 中国科学院大学, 北京, 100049  

3. 中国科学院广州地球化学研究所, 有机地球化学国家重点实验室;;广东省环境保护与资源利用重点实验室, 广州, 510640

语种 中文
文献类型 研究性论文
ISSN 0254-0096
学科 能源与动力工程
基金 国家重点研发计划 ;  国家自然科学基金 ;  广东省自然科学基金
文献收藏号 CSCD:7127188

参考文献 共 24 共2页

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