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Synthesis and luminescence properties of Mn~(3+), Bi~(3+) co-doped Y_6WO_(12) for blue phosphor

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You Junhua 1   Wang Renchao 2,3   Han Fei 2,3   Guo Rui 2,3   Liu Xuanwen 2,3  
文摘 Mn~(3+) and Bi~(3+) co-doped Y_6WO_(12) samples with hexagonal structure were synthesized via an improved salt pyrogenation method at a temperature region of 700–1100 ℃ for 3 h. In Y_6WO_(12), Mn~(3+), substituting Y~(3+), occupies a seven-coordination site and its energy levels are treated in near Oh symmetry. The samples doped by Mn~(3+) alone emit the most intensive blue light at 420 nm under excitation at 247 nm due to charge transition (CT). The mechanism of sensitization of Bi~(3+) for Y_6WO_(12):Mn~(3+) was also analyzed by taking account of metal-to-metal chargetransfer (MMCT) from Bi~(3+) to Mn~(3+). As a consequence, the phosphor Y_6WO_(12):Mn~(3+)/Bi~(3+) can emit blue light under radiation of 370 nm, and the emission intensity is enhanced about five times by the sensitizer Bi~(3+). The optimal doping concentration of Bi~(3+) is determined as 1 at% for the emission at 420 nm in Y_6WO_(12):0.5 at% Mn~(3+) phosphors.
来源 Rare Metals ,2018,37(5):439-446 【核心库】
DOI 10.1007/s12598-018-1039-5
关键词 Mn~(3+) ; Bi~(3+) ; Y_6WO_(12) ; Blue phosphor ; Salt pyrogenation method
地址

1. School of Materials Science and Engineering, Shenyang University of Technology, Shenyang, 110870  

2. School of Resources and Materials, Northeastern University at Qinhuangdao, Qinhuangdao, 066004  

3. Key Laboratory of Nano-Materials and Photoelectric Catalysis of Qinhuangdao, Key Laboratory of Nano-Materials and Photoelectric Catalysis of Qinhuangdao, Qinhuangdao, 066004

语种 英文
文献类型 研究性论文
ISSN 1001-0521
学科 物理学;电子技术、通信技术
基金 国家自然科学基金 ;  the Program for Liaoning Innovative Research Team in University ;  Hebei Province Higher Education Science and Technology Research Project ;  the Scientific and Technological Research and Development Plan of Qinhuangdao City ;  Northeastern University at Qinhuangdao Campus Research Fund
文献收藏号 CSCD:6339862

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