Synthesis and luminescence properties of Mn~(3+), Bi~(3+) co-doped Y_6WO_(12) for blue phosphor
查看参考文献30篇
文摘
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Mn~(3+) and Bi~(3+) co-doped Y_6WO_(12) samples with hexagonal structure were synthesized via an improved salt pyrogenation method at a temperature region of 700–1100 ℃ for 3 h. In Y_6WO_(12), Mn~(3+), substituting Y~(3+), occupies a seven-coordination site and its energy levels are treated in near Oh symmetry. The samples doped by Mn~(3+) alone emit the most intensive blue light at 420 nm under excitation at 247 nm due to charge transition (CT). The mechanism of sensitization of Bi~(3+) for Y_6WO_(12):Mn~(3+) was also analyzed by taking account of metal-to-metal chargetransfer (MMCT) from Bi~(3+) to Mn~(3+). As a consequence, the phosphor Y_6WO_(12):Mn~(3+)/Bi~(3+) can emit blue light under radiation of 370 nm, and the emission intensity is enhanced about five times by the sensitizer Bi~(3+). The optimal doping concentration of Bi~(3+) is determined as 1 at% for the emission at 420 nm in Y_6WO_(12):0.5 at% Mn~(3+) phosphors. |
来源
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Rare Metals
,2018,37(5):439-446 【核心库】
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DOI
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10.1007/s12598-018-1039-5
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关键词
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Mn~(3+)
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Bi~(3+)
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Y_6WO_(12)
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Blue phosphor
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Salt pyrogenation method
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地址
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1.
School of Materials Science and Engineering, Shenyang University of Technology, Shenyang, 110870
2.
School of Resources and Materials, Northeastern University at Qinhuangdao, Qinhuangdao, 066004
3.
Key Laboratory of Nano-Materials and Photoelectric Catalysis of Qinhuangdao, Key Laboratory of Nano-Materials and Photoelectric Catalysis of Qinhuangdao, Qinhuangdao, 066004
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语种
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英文 |
文献类型
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研究性论文 |
ISSN
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1001-0521 |
学科
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物理学;电子技术、通信技术 |
基金
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国家自然科学基金
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the Program for Liaoning Innovative Research Team in University
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Hebei Province Higher Education Science and Technology Research Project
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the Scientific and Technological Research and Development Plan of Qinhuangdao City
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Northeastern University at Qinhuangdao Campus Research Fund
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文献收藏号
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CSCD:6339862
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