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Isothermal reduction kinetics and mineral phase of chromium-bearing vanadium-titanium sinter reduced with CO gas at 873-1273 K

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Yang Songtao 1,2,3   Zhou Mi 1,3   Jiang Tao 1,3   Xue Xiangxin 1,3 *  
文摘 Reduction of chromium-bearing vanadium-titanium sinter (CVTS) was studied under simulated conditions of a blast furnace, and thermodynamics and kinetics were theoretically analyzed. Reduction kinetics of CVTS at different temperatures was evaluated using a shrinking unreacted core model. The microstructure, mineral phase, and variation of the sinter during reduction were observed by X-ray diffraction, scanning electron microscopy, and metallographic microscopy. Results indicate that porosity of CVTS increased with temperature. Meanwhile, the reduction degree of the sinter improved with the reduction rate. Reduction of the sinter was controlled by a chemical reaction at the initial stage and inner diffusion at the final stage. Activation energies measured 29.22-99.69 kJ/mol. Phase transformations in CVTS reduction are as follows: Fe_2O_3→Fe_3O_4→FeO→Fe; Fe_2TiO_5→Fe_2TiO_4→FeTiO_3; FeO V_2O_3→V_2O_3; FeO·Cr_2O_3→Cr_2O_3.
来源 International Journal of Minerals , Metallurgy and Materials,2018,25(2):145-152 【核心库】
DOI 10.1007/s12613-018-1557-z
关键词 sinter ; kinetics ; reduction ; mineral phase
地址

1. School of Metallurgy, Northeastern University, Shenyang, 110819  

2. School of Materials and Metallurgy, University of Science and Technology Liaoning, Anshan, 114051  

3. Key Laboratory of Liaoning Province for Recycling Science of Metallurgical Resources, Key Laboratory of Liaoning Province for Recycling Science of Metallurgical Resources, Shenyang, 110819

语种 英文
文献类型 研究性论文
ISSN 1674-4799
学科 冶金工业
基金 国家自然科学基金 ;  the Fundamental Funds for the Central Universities ;  辽宁省自然科学基金 ;  中国博士后科学基金 ;  the NEU Postdoctoral Science Foundation
文献收藏号 CSCD:6196403

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引证文献 2

1 Tang Weidong Effects of basicity and temperature on mineralogy and reduction behaviors of high-chromium vanadium-titanium magnetite sinters Journal of Central South University,2019,26(1):132-145
被引 3

2 Li Xiaohui Formation of calcium titanate in the carbothermic reduction of vanadium titanomagnetite concentrate by adding CaCO_3 International Journal of Minerals, Metallurgy and Materials,2020,27(6):745-753
被引 2

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