珠江主干和东江河流表层沉积物中有机磷酸酯阻燃剂/增塑剂分布
Occurrence and Distribution of Organophosphorus Flame Retardants / Plasticizer in Surface Sediments from the Pearl River and Dongjiang River
查看参考文献33篇
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文摘
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有机磷酸酯阻燃剂/增塑剂(organophosphate esters, OPs)用量大、环境分布广泛、毒理效应显著,已成为环境领域关注热点。采用超声辅助提取结合固相萃取技术和气相色谱-质谱分析,研究珠江主干和东江河流表层样品中7种常见OPs含量水平与分布特征。结果表明,研究区域沉积物中OPs分布广泛,珠江主干Σ7OPs范围为78.9~ 577 ng·g~(-1),主要污染物为磷酸三(丁氧基乙基)酯(TBEP),其次为磷酸三丁酯(TBP)和磷酸三(2-氯)乙酯(TCEP),均值分别为84.6 ng·g~(-1)、55.6 ng·g~(-1)和27.8 ng· g~(-1);东江河段沉积物中Σ7OPs含量范围为24.0~ 293 ng·g~(-1),以磷酸三甲苯酯(TTP)、磷酸三苯酯(TPhP)和TBEP为主要污染物,平均浓度分别为55.6 ng·g~(-1)、32.7 ng·g~(-1)和17.5 ng·g~(-1)。以上结果揭示了珠江和东江沉积物中有机磷阻燃剂/增塑剂的浓度和分布是明显不同的,可能与不同来源的点源排放有关。 |
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其他语种文摘
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Due to their widespread application, ubiquitous distribution in the environment, and significant toxicological effect, organophosphate esters (OPs) have attracted increasing concern. Seven widely used organophosphorus flame retardants/plasticizer in surface sediments from the Pearl River and Dongjiang River were ultrasonically extracted, enriched via solid phase extraction, and analyzed by gas chromatography-mass spectrometry. OPs were widely detected in all sediment samples in the studied region. Concentrations of Σ7OPs varied in the range of 78.9 ~ 577 ng·g~(-1) in the Pearl River, and tris-(2-butoxyethyl) phosphate (TBEP), tributyl phosphate (TBP) and tris-(2-chloroethyl) phosphate (TCEP) were the main components with average concentrations at 84.6 ng·g~(-1), 55.6 ng·g~(-1) and 27.8 ng·g~(-1), respectively. Concentrations of Σ7OPs varied in the range of 24.0 ~ 293 ng·g~(-1) in the Dongjiang River, and tritolyl phosphate (TTP), triphenyl phosphate (TPhP) and TBEP were the dominant compounds with average concentrations at 55.6 ng·g~(-1), 32.7 ng·g~(-1) and 17.5 ng·g~(-1). The above result suggested the significant difference in the levels and distribution of OPs between the sediments from the Pearl River and the Dongjiang River, which might depend on their spot emission from different discharges. |
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来源
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生态毒理学报
,2016,11(2):436-443 【核心库】
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DOI
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10.7524/AJE.1673-5897.20150915001
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关键词
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有机磷酸酯
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珠江主干
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东江
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沉积物
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地址
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1.
中国科学院广州地球化学研究所, 有机地球化学国家重点实验室;;广东省环境资源利用与保护重点实验室, 广州, 510640
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广州禾信分析仪器有限公司, 广州, 510530
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语种
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中文 |
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文献类型
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研究性论文 |
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ISSN
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1673-5897 |
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学科
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环境科学基础理论 |
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基金
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广东省科技计划项目
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国家自然科学基金项目
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文献收藏号
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CSCD:5766967
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参考文献 共
33
共2页
|
|
1.
European Flame Retardants Association.
Introduction of flame retardants,2006
|
被引
1
次
|
|
|
|
|
2.
Stapleton H M. Detection of organophosphate flame retardants in furniture foam and U.S. house dust.
Environmental Science & Technology,2009,43(19):7490-7495
|
被引
35
次
|
|
|
|
|
3.
European Flame Retardants Association.
Introduction of flame retardants,2009
|
被引
1
次
|
|
|
|
|
4.
Van der Veen I. Phosphorus flame retardants: Properties, production, environmental occurrence, toxicity and analysis.
Chemosphere,2012,88(10):1119-1153
|
被引
164
次
|
|
|
|
|
5.
王晓伟. 有机磷酸酯阻燃剂污染现状与研究进展.
化学进展,2010,22(10):1983-1992
|
被引
51
次
|
|
|
|
|
6.
Rodil R. Emerging pollutants in sewage, surface and drinking water in Galicia (NW Spain).
Chemosphere,2012,86(10):1040-1049
|
被引
30
次
|
|
|
|
|
7.
Harino H. Current status of organophosphorus compounds contamination in Maizuru Bay, Japan.
Marine Biological Association of the United Kingdom,2014,94(1):43-49
|
被引
3
次
|
|
|
|
|
8.
Wang X. Rapid quantification of highly polar trimethyl phosphate in wastewater via direct analysis in real-time mass spectrometry.
Journal of Chromatogr A,2014,1333:134-137
|
被引
3
次
|
|
|
|
|
9.
Shoeib M. Concentrations in air of organobromine, organochlorine and organophosphate flame retardants in Toronto, Canada.
Atmospheric Environment,2014,99:140-147
|
被引
11
次
|
|
|
|
|
10.
Ali N. Levels and profile of several classes of organic contaminants in matched indoor dust and serum samples from occupational settings of Pakistan.
Environmental Pollution,2014,193:269-276
|
被引
7
次
|
|
|
|
|
11.
Chen D. Determination of non-halogenated, chlorinated and brominated organophosphate flame retardants in herring gull eggs based on liquid chromatography-tandem quadrupole mass spectrometry.
Journal of Chromatography A,2012,1220:169-174
|
被引
20
次
|
|
|
|
|
12.
Araki A. Phosphorus flame retardants in indoor dust and their relation to asthma and allergies of inhabitants.
Indoor Air,2013,24(1):3-15
|
被引
15
次
|
|
|
|
|
13.
胡晓辉. 环境中有机磷酸酯阻燃剂分析方法的研究进展.
环境化学,2014,33(12):2076-2086
|
被引
13
次
|
|
|
|
|
14.
梁钪. 超高效液相色谱-串联质谱法测定污水中14种有机磷酸酯阻燃剂.
环境化学,2014,10:1681-1685
|
被引
1
次
|
|
|
|
|
15.
温家欣.
有机磷酸酯阻燃剂的分离分析技术及其应用研究,2010
|
被引
5
次
|
|
|
|
|
16.
Cao S X. Levels and distributions of organophosphate flame retardants and plasticizers in sediment from Taihu Lake, China.
Environmental Toxicology and Chemistry,2012,31(7):1478-1484
|
被引
11
次
|
|
|
|
|
17.
Fu J M. Persistent organic pollutants in environment of the Pearl River Delta, China: An overview.
Chemosphere,2003,52(9):1411-1422
|
被引
95
次
|
|
|
|
|
18.
麦碧娴. 珠江三角洲沉积物中毒害有机物的污染现状及评价.
环境科学研究,2001(1):19-23
|
被引
51
次
|
|
|
|
|
19.
Stachel B. The Elbe Flood in August 2002-Organic contaminants in sediment samples taken after the flood event.
Journal of Environmental Science and Health, Part A,2005,40(2):265-287
|
被引
5
次
|
|
|
|
|
20.
Zeng X Y. Occurrence and distribution of organophosphate flame retardants/plasticizers in wastewater treatment plant sludges from the Pearl River Delta, China.
Environmental Toxicology and Chemistry,2014,33(8):1720-1725
|
被引
11
次
|
|
|
|
|
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