新疆卡鲁安矿区807号伟晶岩脉近脉围岩蚀变中成矿元素扩散模型及其影响因素
Altered country rocks of No. 807 pegmatite vein in the Kalu'an ore area, Xinjiang: Ore-forming element diffusion model and its influencing factors
查看参考文献29篇
文摘
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通过对新疆卡鲁安矿区807号伟晶岩脉体蚀变围岩样品的研究,发现主元素Fe203、A1203、K_2O、 TiO_2,微量元素Li、Rb、Cs、Be等的含量在距接触带0.5 m处出现极大值,向围岩方向元素含量逐渐减少,主元素SiO_2含量则表现出相反的变化情况;同时蚀变围岩中发育白云母化和电气石化蚀变,结合矿相学及探针数据分析,认为围岩中可能发生3NaAlSi_3O_8+2H~++K~+=KAl_3Si_30_(10)(OH)_2+3Na~++6SiO_2和2KFe_3(AlSi_3O_(10))(OH)_2+ SiO_2+5Al_2SiO_5+2Na~++6H_3B0_3 = 2NaFe_3Al_6[Si_6O_(18)][BO_3]_3(0H)_4+2K~++7H_2O等反应。对蚀变围岩中组分含量变化率和距接触带的距离的关系进行拟合,结果表明蚀变围岩中组分的迁移方式以扩散为主,组分含量变化率是影响扩散距离的主要因素,有效扩散系数和扩散时间起次要作用,同时组分的扩散时间和扩散距离呈正比。从807号脉蚀变围岩Isocon图解可看出Li、Rb、Cs等元素具有较高的迁入率,与前人研究的Li、Rb、 Cs具有较高的活动性的结论相一致。 |
其他语种文摘
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Based on our studies on altered country rock samples from No.807 pegmatite vein in Kalu'an ore area in Xinjiang, it is found that major element oxides such as Fe_2O_3,Al_2O_3, K_2O, TiO_2 and trace elements such as Li, Rb, Cs, Be reach their maximum contents at approximately 0.5m away from the contact zone between the pegmatite vein and the country rocks, and tend to decrease in the direction from the contact zone to the country rocks, while the content of SiO_2 shows an opposite tendency of variation. On the basis of the available mineralogical and electron probe analytical data, the occurrence of muscovite and tourmaline in the altered rocks probably indicates the following reactions, e.g., 3NaAlSi_3O_8+2H~++K~+=KAl_3Si_3O_(10)(OH)_2+3Na~++6SiO_2 and 2KFe_3(AlSi_3O_(10))(OH)_2+ SiO_2+5Al_2SiO_5+2Na~++6H_3B0_3=2NaFe_3Al_6[Si_6O_(18)][BO_3]_3(OH)_4+2K~++7H_2O. By employing the data fitting of variation rates of component contents and the corresponding distance away from the contact zone, it is suggested that the component migration patterns are controlled mainly by diffusion. Among the factors that influence the diffusion distance, the variation rate for component contents is the primary factor, while both effective diffusion coefficient and diffusion time are the secondary factors. Meanwhile, we found have that the diffusion time is proportional to the diffusion distance. The Isocon diagram for the altered country rocks of No.807 pegmatite vein shows that elements such as Li, Rb and Cs exhibit higher migration rates, which is consistent with the results of the previous study that Li, Rb and Cs exhibit much higher mobility. |
来源
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地球化学
,2016,45(3):268-280 【核心库】
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关键词
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稀有金属
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扩散模型
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围岩蚀变
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伟晶岩
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阿尔泰
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地址
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中国科学院地球化学研究所, 地球内部物质高温高压重点实验室, 贵州, 贵阳, 550002
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语种
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中文 |
文献类型
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研究性论文 |
ISSN
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0379-1726 |
学科
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地质学 |
基金
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国家自然科学基金
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新疆有色金属工业集团地质科研项目
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文献收藏号
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CSCD:5713516
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