二氧化硅表面修饰硅烷偶联剂APTS的过程和机制
Process and mechanism of surface modification of silica with silane coupling agent APTS
查看参考文献52篇
文摘
|
二氧化硅表面经过硅烷偶联剂g-氨丙基三乙氧基硅烷(APTS)修饰后,在橡胶、塑料、催化剂、色谱柱、吸附剂、生物和医药等领域中具有独特的应用性能,大量文献结合特定应用体系研究二氧化硅表面修饰APTS的基本规律,以实现理想可控的修饰效果。总结这些分散性研究结果,有利于在新的基础上有效地促进研究的深入。在分析文献的基础上,系统地阐述了二氧化硅表面修饰APTS的反应机理、修饰工艺、反应动力学、修饰层稳定性和结构形貌等方面的研究进展,提出了目前研究还存在的问题和进一步的研究方向。 |
其他语种文摘
|
After modification using gamma aminopropyltriethoxysilane (APTS), the silica surface demonstrates unique performance in the applications to rubber, plastics, catalyst, chromatography column, adsorbent, biologicals and pharmaceuticals. A large number of literatures focus on APTS modification of silica in the specific application background for achieving ideal and controllable modification. Summarizing these scattered results and discoveries can effectively promote research further on a new stage. Based on an analysis of literatures, the mechanism of reaction, process of modification, kinetics of reaction, stability and structure of the modified layer are reviewed. The existing problems in the current state of the research and the directions for further research are proposed. |
来源
|
化工学报
,2014,65(7):2629-2637 【核心库】
|
DOI
|
10.3969/j.issn.0438-1157.2014.07.022
|
关键词
|
二氧化硅
;
表面
;
多相反应
;
硅烷偶联剂
;
接枝
;
修饰
|
地址
|
清华大学化学工程系, 北京, 100084
|
语种
|
中文 |
文献类型
|
综述型 |
ISSN
|
0438-1157 |
学科
|
化学工业 |
基金
|
国家自然科学基金项目
|
文献收藏号
|
CSCD:5183270
|
参考文献 共
52
共3页
|
1.
Plueddemann E P.
Silane Coupling Agents (2nd ed),1991:153-249
|
被引
1
次
|
|
|
|
2.
王奂玲. 氨丙基官能化SBA-15介孔分子筛的合成及催化性能的研究.
分子催化,2005,19(1):1-6
|
被引
13
次
|
|
|
|
3.
O'Gara J E. Embedded-polar-group bonded phases for high performance liquid chromatography.
LC GC North America,2001,19(6):632
|
被引
4
次
|
|
|
|
4.
Vansant E F.
Characterization and Chemical Modification of the Silica Surface,1995
|
被引
4
次
|
|
|
|
5.
Etienne M. Analytical investigation of the chemical reactivity and stability of aminopropyl-grafted silica in aqueous medium.
Talanta,2003,59(6):1173-1188
|
被引
8
次
|
|
|
|
6.
Jal P K. Chemical modification of silica surface by immobilization of functional groups for extractive concentration of metal ions.
Talanta,2004,62(5):1005-1028
|
被引
34
次
|
|
|
|
7.
Walcarius A. Uptake of inorganic Hg~(II) by organically modified silicates: influence of pH and chloride concentration on the binding pathways and electrochemical monitoring of the processes.
Analytica Chimica Acta,2004,508(1):87-98
|
被引
2
次
|
|
|
|
8.
Klonkowski A M. The coordination state of copper(Ⅱ) complexes anchored and grafted onto the surface of organically modified silicates.
Langmuir,1999,15(18):5814-5819
|
被引
3
次
|
|
|
|
9.
Oh S. Preparation of novel ceramic membranes modified by mesoporous silica with 3-aminopropyltriethoxysilane (APTES) and its application to Cu~(2+) separation in the aqueous phase.
Journal of Membrane Science,2007,301(1/2):118-125
|
被引
5
次
|
|
|
|
10.
Briand E. Chemical modifications of Au/SiO_2 template substrates for patterned biofunctional surfaces.
Langmuir,2011,27(2):678-685
|
被引
5
次
|
|
|
|
11.
Kim J. Investigations of chemical modifications of amino-terminated organic films on silicon substrates and controlled protein immobilization.
Langmuir,2010,26(4):2599-2608
|
被引
6
次
|
|
|
|
12.
Levy L. Nanochemistry: synthesis and characterization of multifunctional nanoclinics for biological applications.
Chemistry of Materials,2002,14(9):3715-3721
|
被引
9
次
|
|
|
|
13.
Liu Z G. Imaging DNA molecules on mica surface by atomic force microscopy in air and in liquid.
Microscopy Research and Technique,2005,66(4):179-185
|
被引
4
次
|
|
|
|
14.
Nehilla B J. Neurotransmitter analog tethered to a silicon platform for neuro-BioMEMS applications.
Biotechnology and Bioengineering,2004,87(5):669-674
|
被引
3
次
|
|
|
|
15.
Takei T. Infrared spectra of geminal and novel triple hydroxyl groups on silica surface.
Colloids and Surfaces A: Physicochemical and Engineering Aspects,1999,150(1/2/3):77-84
|
被引
3
次
|
|
|
|
16.
Yermakov Y L.
Catalysis by Supported Complexes,1981:59-61
|
被引
2
次
|
|
|
|
17.
Ek S. A 29Si and 13C CP/MAS NMR study on the surface species of gas-phase-deposited γ-aminopropylalkoxysilanes on heat-treated silica.
The Journal of Physical Chemistry B,2004,108(31):11454-11463
|
被引
4
次
|
|
|
|
18.
Acres R G. Molecular structure of 3-aminopropyltriethoxysilane layers formed on silanol-terminated silicon surfaces.
Journal of Physical Chemistry C,2012,116(10):6289-6297
|
被引
10
次
|
|
|
|
19.
Zhu M J. How to prepare reproducible, homogeneous, and hydrolytically stable aminosilane-derived layers on silica.
Langmuir,2012,28(1):416-423
|
被引
4
次
|
|
|
|
20.
Vrancken K C. Modelling of the reaction-phase interaction of γ-aminopropyltriethoxysilane with silica.
J. Chem. Soc., Faraday Trans,1993,89:2037-2040
|
被引
2
次
|
|
|
|
|