博斯腾湖沉积物孔隙水中溶解有机质的三维荧光光谱特征
3D Fluorescence Spectroscopy of Dissolved Organic Matter in Sediment Pore Water of the Bosten Lake
查看参考文献24篇
文摘
|
运用三维分子荧光光谱法,研究博斯腾湖中的天然溶解有机质(DOM)。结果显示:博斯腾湖沉积物孔隙水DOM出现了2~4个明显的荧光峰,峰A和峰C为类蛋白峰,峰B为类富里酸峰,峰D为类腐殖酸峰。博斯腾湖不同采样点沉积物孔隙水DOM中类蛋白物质荧光强度普遍高于类腐殖质(富里酸和腐殖酸)荧光强度。各峰荧光强度从黄水沟人湖口到湖中心呈下降趋势。盐度与各采样点的DOM荧光特征没有明显的相关性。DOM荧光强度随着沉积深度总体呈上升趋势。博斯腾湖沉积物孔隙水DOM的r (B/D)(富里酸峰与腐殖酸峰荧光强度比)平均值为1.01,腐殖质荧光强度较稳定,有机质结构和成熟度变化不明显,可能源自同一个。荧光指数平均值为1.82,说明其DOM中的腐殖质主要源于生物输入。 |
其他语种文摘
|
Fluorescence characteristics of dissolved organic matter (DOM) in sediment pore water of the Bosten Lake were investigated using the 3D fluorescence spectroscopy. There were 2-4 fluorescence peaks in the fluorescence spectra of the samples. Peaks A and C were the protein peaks, peak B was the fulvic acid peak, and peak D the humic acid peak. At the sampling sites from No. 1 to No. 10, the fluorescence intensity of peaks A and C was higher than peaks B and D. Fluorescence intensity of all peaks was generally in a decrease trend from the entrance to the lake center. There was no the significant correlation between salinity and fluorescence intensity. Fluorescence intensity of DOM in pore water was increased with the increase of sediment depth. Average value of r (B/D) was 1.01.Humic fluorescence intensity was stable, and the change of organic matter structure and maturity was not significant, indicating that they might come from the same source. Fluorescence intensity ranged from 1.80 to 2.10, and its average was 1.82, These revealed that DOM in the Bosten Lake originated from biological sources. These novel findings are important in studying the sources, properties and interaction with pollutants of DOM in aquatic environment. |
来源
|
干旱区研究
,2014,31(1):176-181 【核心库】
|
关键词
|
DOM
;
荧光强度
;
三维荧光光谱
;
沉积物
;
孔隙水
;
博斯腾湖
;
新疆
|
地址
|
1.
中国科学院新疆生态与地理研究所, 荒漠与绿洲生态国家重点实验室, 新疆, 乌鲁木齐, 830011
2.
中国科学院地球化学研究所, 环境地球化学国家重点实验室, 贵州, 贵阳, 550002
|
语种
|
中文 |
文献类型
|
研究性论文 |
ISSN
|
1001-4675 |
基金
|
中国科学院西部之光人才培养计划
;
国家自然科学基金项目
|
文献收藏号
|
CSCD:5042289
|
参考文献 共
24
共2页
|
1.
徐海量. 新疆博斯腾湖水污染特点分析.
干旱区研究,2003,20(3):192-196
|
被引
4
次
|
|
|
|
2.
陈发虎. 新疆博斯腾湖记录的亚洲内陆干旱区小冰期湿润气候研究.
地球科学,2007,37(1):77-85
|
被引
1
次
|
|
|
|
3.
买合木提·巴拉提. 博斯腾湖排污现状和污染物总量控制.
新疆环境保护,2003,25(2):34-36
|
被引
3
次
|
|
|
|
4.
盛东. 干旱区内陆湖泊水盐变化及调控机理.
干旱区研究,2010,27(4):529-535
|
被引
9
次
|
|
|
|
5.
欧文佳. 博斯腾湖现代沉积特征及其环境意义.
干旱区研究,2012,29(4):721-726
|
被引
3
次
|
|
|
|
6.
罗莎莎. 云南洱海沉积物──水界面铁、锰的分布和迁移特征.
重庆环境科学,2000,22(6):19-21
|
被引
16
次
|
|
|
|
7.
Mopper K. Fluorescence as a possible tool for studying the nature and water column distribution of DOC components.
Marine Chemistry,1993,41:229-238
|
被引
48
次
|
|
|
|
8.
Yamashita Y. Chemical characterization of protein like fluorescence in DOM in relation to aromatic amino acids.
Marine Chemistry,2003,82:255-271
|
被引
84
次
|
|
|
|
9.
Chen Wen. Fluorescence excitation-emission matrix regional integration to quantify spectra for dissolved organic matter.
Environmental Science Technology,2003,37(24):5701-5710
|
被引
794
次
|
|
|
|
10.
Pan Xiangliang. Cu (Ⅱ) complexation of high molecular weight (HMW) fluorescent substances in root exudates from a wetland halophyte.
Journal of Bioscience and Bioengineering,2011,111(2):193-197
|
被引
4
次
|
|
|
|
11.
Ding Fei. Chloramphenicol constants and binding sites by steady-state fluorescence.
Journal of Molecular Structure,2009,929(3):159-166
|
被引
12
次
|
|
|
|
12.
胡春明. 太湖典型湖区水体溶解有机质的光谱学特征.
光谱学与光谱分析,2011,31(1):3021-3025
|
被引
1
次
|
|
|
|
13.
Kristiansen E. Aerobic and anaerobic decomposition of organic matter in marine sediment.
Limnology and Oceanography,1995,40(8):1430-1437
|
被引
10
次
|
|
|
|
14.
彭全材. 百花湖沉积物孔隙水中溶解有机质的光谱特征.
江西师范大学学报,2009,33(3):261-266
|
被引
4
次
|
|
|
|
15.
祝鹏. 太湖溶解有机质光谱和氮磷污染的区域分布差异特征.
环境科学研究,2010,23(2):128-136
|
被引
1
次
|
|
|
|
16.
江莉. 淡水微生物对Q235钢早期腐蚀行为的影响.
中国腐蚀与防护学报,2009,29(3):177-180
|
被引
2
次
|
|
|
|
17.
王亚俊. 20世纪50年代以来博斯腾湖水盐变化及趋势.
干旱区研究,2005,22(3):355-400
|
被引
24
次
|
|
|
|
18.
Hudson N. Fluorescence analysis of dissolved organic-matter in natural waste and polluted waters: A review.
River Research and Applications,2007,23(6):631-649
|
被引
79
次
|
|
|
|
19.
Swietlik J. Application of fluorescence spectroscopy in the studies of natural organic matter fractionsreactivity with chlorine dioxide and ozone.
Water Research,2004,38(17):3791-3799
|
被引
44
次
|
|
|
|
20.
Cowie G L. Organic content and preservational controls in surficial shelf and slope sediments from the Arabian Sea (Pakistan Margin).
Marine Geology,1999,161:23-38
|
被引
2
次
|
|
|
|
|