表生风化淋滤迁移过程的Cd同位素分馏及其指示意义
Cadmium Isotopic Fractionation during the Supergenic Weathering and Leaching Process and Its Implication
查看参考文献16篇
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文摘
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利用Cd同位素来示踪Cd污染源是近年发展起来的一个新的同位素示踪体系,具有极大的优越性。然而,在利用Cd同位素示踪污染源的研究中,表生风化淋滤作用是否会导致同位素分馏,目前还没有研究报导,限制了Cd同位素在示踪污染源方面的应用。通过对Pb-Zn矿山主要固体污染源的表生风化淋滤过程进行模拟实验表明,无论是淋滤实验还是可交换态 Cd实验,淋滤液总体上较残留态富集Cd的重同位素,其中尤以硫化矿最为明显,其Cd同位素分馏可达0.50‰(δ~(114/110) Cd)。此外,Cd的淋滤率与淋滤产生的Cd同位素分馏总体呈负相关关系。因此,我们认为在利用Cd同位素端元模型示踪污染源时,必须充分考虑表生风化淋滤作用可能带来的影响。 |
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其他语种文摘
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Cd isotopes have been useful proxies to trace the pollution sources, which show apparent advantages in the field study. However, it is not well known whether the supergenic weathering and leaching process could cause Cd isotope fractionation or not, which hampers the applications of Cd isotopes to tracing the pollution sources. Leaching experiments and exchangeable Cd experiments on different typical samples from lead-zinc mines shoned that the leached liquids always favor heavier Cd isotopes than the corresponding residuals. The obvious Cd isotope fractionation between leached liquids and residual could come up to about 0.50‰, which was observed in the sulfide samples. Meanwhile, a negative correlation between the Cd concentrations in leached liquids and the δ~(114/110) Cd values was found in this study. These results suggested that when Cd isotopes are used to trace the pollution sources, the isotope fractionation from the supergenic weathering process must be taken into consideration. |
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来源
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地球与环境
,2013,41(6):612-617 【核心库】
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关键词
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Cd同位素
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淋滤实验
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重金属污染
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同位素示踪
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地址
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1.
中国科学院地球化学研究所, 矿床地球化学国家重点实验室, 贵阳, 550002
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中国科学院地球环境研究所, 黄土与第四纪地质国家重点实验室, 西安, 710075
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语种
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中文 |
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文献类型
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研究性论文 |
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ISSN
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1672-9250 |
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学科
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地质学;环境科学基础理论 |
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基金
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国家自然科学基金项目
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文献收藏号
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CSCD:5017136
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参考文献 共
16
共1页
|
|
1.
Rosman K J R. Isotopic evidence for the source of lead in Greenland snows since the late 1960s.
Nature,1993,362:333-335
|
被引
3
次
|
|
|
|
|
2.
Hansmann W. Lead-isotopes as tracers of pollutants in soils.
Chemical Geology,2000,171:123-144
|
被引
24
次
|
|
|
|
|
3.
Cloquet C. Atmospheric pollutant dispersal around an urban area using trace metal concentrations and Pb isotopic compossitions in epiphytic lichens.
Atmospheric Environment,2006,40:574-587
|
被引
10
次
|
|
|
|
|
4.
Cloquet C. Tracing source pollution in soils using cadmium and lead isotopes.
Environmental Science and Technology,2006,40:2525-2530
|
被引
38
次
|
|
|
|
|
5.
Shiel A E. Tracing cadmium,zinc and lead sources in bivalves from the coasts of western Canada and the USA using isotopes.
Geochimica et Cosmochimica Acta,2012,76:175-190
|
被引
8
次
|
|
|
|
|
6.
潘自平. 近中性溶液条件下富镉铅锌矿矿石的风化淋滤实验研究.
矿物学报,2007,7(S1):558-562
|
被引
1
次
|
|
|
|
|
7.
张羽旭. Cd同位素地质样品的预处理方法研究.
分析测试学报,2010,29(6):633-637
|
被引
9
次
|
|
|
|
|
8.
Cloquet C. Natural cadmium isotopic variations in eight geological reference materials(NIST SRM 2711,BCR 176,GSS-1,GXR-1,GXR-2,GSD-12,Nod-p-1,Nod-A-1)and anthropogenic samples,measured by MC-ICP-MS.
Geostandards and Geoanalytical Research,2005,29:95-106
|
被引
20
次
|
|
|
|
|
9.
Lacan F. Cadmium isotopic composition in the ocean.
Geochimica et Cosmochimica Acta,2006,70:5104-5118
|
被引
16
次
|
|
|
|
|
10.
Ripperger S. Cadmium isotope fractionation in seawater-A signature of biological activity.
Earth and Planetary Science Letters,2007,261:670-684
|
被引
19
次
|
|
|
|
|
11.
Schmitt A D. Mass-dependent cadmium isotopic variations in nature with emphasis on the marine environment.
Earth and Planetary Science Letters,2009,277:262-272
|
被引
13
次
|
|
|
|
|
12.
Wombacher F. Determination of the mass-dependence of cadmium isotope fractionation during evaporatio.
Geochimica et Cosmochimica Acta,2004,68(10):2349-2357
|
被引
13
次
|
|
|
|
|
13.
Fernandez A. Fractionation of Cu,Fe,and Zn isotopes during the oxidative weathering of sulfide-rich rocks.
Chemical Geology,2009,264:1-12
|
被引
23
次
|
|
|
|
|
14.
John S G. Zinc stables isotopes in seafloor hydrothermal vent fluids and chimneys.
Earth and Planetary Science Letters,2008,269:17-28
|
被引
28
次
|
|
|
|
|
15.
Gao B. Precise determination of cadmium and lead isotopic compositions in river sediments.
Analytica Chimica Acta,2008,612:114-120
|
被引
20
次
|
|
|
|
|
16.
Shiel A E. Evaluation of zinc,cadmium and lead isotope fractionation during smelting and refining.
Science of the Total Environment,2010,408:2357-2368
|
被引
14
次
|
|
|
|
|
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