Chernin型多通池用于烟雾箱光化学反应过程的实验研究
Experimental Study of the Photochemical Reaction in the Smog Chamber Using a Chernin Multipass Cell
查看参考文献27篇
文摘
|
将Chernin型多通吸收光谱系统与光化学模拟烟雾箱系统相结合,用于烟雾箱内痕量气体的探测,系统的准确性及可靠性通过NO_2的测量进行验证,NO_2的探测结果与Thermo 42i型NO-NO_2-NO_x分析仪的测量结果呈较好的线性关系。对烟雾箱内β蒎烯/O_3/SO_2体系化学反应过程中SO_2的摩尔分数做了在线测量,在36 m的吸收光程内,SO_2的探测极限为22.2×10~(-9)。研究结果表明,该Chernin型多通吸收光谱系统具有定量测量能力,能够用于烟雾箱内光化学反应过程中痕量成分的实时在线测量。 |
其他语种文摘
|
A Chernin multipass absorption spectroscopy system is combined with the photochemical simulation smog chamber and applied to the detection of trace gases in the smog chamber. The system accuracy and reliability are proved with NO_2 detection. The NO_2 measurements of the system and the results of Thermo 42i NO-NO_2-NO_x analyzer have a good linear relationship. The system is applied to online detection of SO_2 during β-pinene/O_3/SO_2 system chemical reaction in the smog chamber and with 36 m absorption path length, the SO_2 detection limit of the system is 22.2×10~(-9). The result demonstrates that the Chernin multipass absorption spectroscopy system has the capability of quantitative measurement and can be used in online detection of trace gases during photochemical reactions in the smog chamber. |
来源
|
光学学报
,2013,33(8):0830001-1-08230001-8 【核心库】
|
DOI
|
10.3788/aos201333.0830001
|
关键词
|
光谱学
;
Chernin多通池
;
烟雾箱
;
SO2
|
地址
|
1.
中国科学院安徽光学精密机械研究所, 中国科学院大气成分与光学重点实验室, 安徽, 合肥, 230031
2.
南京信息工程大学物理与光电工程学院, 江苏, 南京, 210044
|
语种
|
中文 |
文献类型
|
研究性论文 |
ISSN
|
0253-2239 |
学科
|
物理学 |
基金
|
国家自然科学基金
;
江苏省自然科学基金
;
安徽省自然科学基金
;
中国科学院安徽光学精密机械研究所所长基金
;
中国科学院大气成分与光学重点实验室2010年开放课题
|
文献收藏号
|
CSCD:4927844
|
参考文献 共
27
共2页
|
1.
Du L. Rate constant for the reaction of ozone with diethyl sulfide.
Atmos Environ,2007,41(35):7434-7439
|
被引
12
次
|
|
|
|
2.
Pan G. Direct detection of isoprene photooxidation products by using synchrotron radiation photoionization mass spectrometry.
Rapid Commun Mass Spectrom,2012,26(2):189-194
|
被引
6
次
|
|
|
|
3.
Huang M. Theoretical investigation on the detailed mechanism of the OH-initiated atmospheric photooxidation of oxylene.
International J Quantum Chemistry,2008,108(5):954-966
|
被引
2
次
|
|
|
|
4.
Gai Y. Kinetics of the gas-phase reactions of some unsaturated alcohols with Cl atoms and O3.
Atmos Environ,2011,45(1):53-59
|
被引
3
次
|
|
|
|
5.
胡高硕. 烟雾箱模拟丙烯-NO_x的大气光化学反应.
化学学报,2011,69(14):1593-1600
|
被引
10
次
|
|
|
|
6.
Takekawa H. Temperature dependence of secondary organic aerosol formation by photo-oxidation of hydrocarbons.
Atmos Environ,2003,37(24):3413-3424
|
被引
31
次
|
|
|
|
7.
Cocker D R. State-of-the-art chamber facility for studying atmospheric aerosol chemistry.
Environ Sci Technol,2001,35(12):2594-2601
|
被引
10
次
|
|
|
|
8.
Wu S. Construction and characterization of an atmospheric simulation smog chamber.
Advances in Atmospheric Sciences,2007,24(2):250-258
|
被引
22
次
|
|
|
|
9.
吴丰成. 利用O_4测量去除车载差分吸收光谱测量污染源NO_2排放通量计算中多次散射的影响.
光学学报,2011,31(11):1101003
|
被引
6
次
|
|
|
|
10.
李昂. 被动差分光学吸收光谱法监测污染源排放总量研究.
光学学报,2007,27(9):1537-1542
|
被引
17
次
|
|
|
|
11.
Hao N. Observations of nitrous acid and its relative humidity dependence in Shanghai.
J Environmental Sciences,2006,18(5):910-915
|
被引
10
次
|
|
|
|
12.
Chernin S M. Development of optical multipass matrix systems.
J Mod Opt,2001,48(4):619-632
|
被引
3
次
|
|
|
|
13.
Glowacki D R. Design and performance of a throughput-matched, zero-geometric-loss, modified three objective multipass matrix system for FTIR spectrometry.
Appl Opt,2007,46(32):7872-7883
|
被引
6
次
|
|
|
|
14.
杨西斌. 一种新型光学多通池系统应用于烟雾箱内挥发性有机化合物探测.
物理学报,2010,59(7):5154-5162
|
被引
7
次
|
|
|
|
15.
周斌. 差分吸收光谱法测量大气污染的浓度反演方法研究.
物理学报,2001,50(9):1818-1823
|
被引
46
次
|
|
|
|
16.
Bogumil K. Measurements of molecular absorption spectra with the SCIAMACHY pre-flight model: instrument characterization and reference data for atmospheric remote-sensing in the 230-2380 nm region.
J Photochem Photobiol A: Chem,2003,157(2/3):167-184
|
被引
32
次
|
|
|
|
17.
Vandaele A. SO2 absorption cross section measurement in the UV using a Fourier transform spectrometer.
J Geophys Res,1994,99(D12):25599-25605
|
被引
6
次
|
|
|
|
18.
Bongartz A. Experimental determination of HONO mass accommodation coefficients using two different techniques.
J Atmos Chem,1994,18(2):149-169
|
被引
5
次
|
|
|
|
19.
吴涛. 基于LED的非相干宽带腔增强吸收光谱技术.
光谱学与光谱分析,2008,28(11):2469-2472
|
被引
5
次
|
|
|
|
20.
Edner H. Differential optical absorption spectroscopy (DOAS) system for urban atmospheric pollution monitoring.
Appl Opt,1993,32(3):327-333
|
被引
13
次
|
|
|
|
|