模拟不同气候条件下碳酸盐岩风化作用的淋溶实验研究
Leaching experiment for the weathering of carbonate rocks by simulating different climates
查看参考文献42篇
|
文摘
|
通过模拟干热、湿热与干冷3种气候条件,以饱和CO_2水作为淋溶液,对.黔中岩溶区3条碳酸盐岩风化壳岩-土界面的岩粉层试样进行了淋溶实验(其中干热、湿热条件下淋溶到残余酸不溶物阶段),对淋出液的pH值以及主要造岩元素的浓度进行了动态分析。结果表明,碳酸盐岩风化壳岩-土界面由岩到土的转变过程中,伴随碳酸盐的溶蚀,酸不溶物已表现出明显的风化傾向。碳酸盐的溶蚀强度表现为干冷>干热>湿热的变化趋势。温度低,碳酸盐的溶解速率大;排水条件好,碳酸盐溶解释放的Ca、Mg易随风化流体排出体系。对于酸不溶物组分,淋溶实验中有:(1)K、Na、Mg、Si、P的载体矿物风化强度在干热条件下最大(至于Ca,由于方解石与白云石均是其主要的载体矿物,酸不溶物相中的Ca难以在淋出液中有效识别)。在干冷与湿热之同,K、Na、Mg等盐基离子的溶出能力大多表现为湿热>干冷,指示了温度对盐基离子释放强度的重要制约作用;而Si和P未表现出一致的变化趋势,可能源于淋溶体系微环境的差异。(2)Fe与Mn表现出弱迁移性。其中,Fe在干冷环境下淋出强度最弱,说明温度是制约含Fe矿物分解速率的重要因素。而Fe在干热与湿热之间,以及Mn在3种淋溶条件下,未呈现出一致的变化趋势。(3)A1和Ti在碳酸盐岩风化过程中表现出强烈的惰性。 |
|
其他语种文摘
|
By simulating dry-hot, wet-hot and dry-cool climate respectively and taking water saturated with CO2 as leaching solution, a leaching experiment is carried out (of them, leaching experiment simulating dryhot and wet-hot climate reached acid-insoluble residue stage) on rock powder layer samples from rocksoil interface in 3 weathering profiles in central Guizhou karst region. The results indicate that acid-insoluble residues have shown significant weathering tendency along with carbonate issolutionatrockoil.interface of weathering profiles. In three kinds of different leaching conditions, the dissolution intensity of arbonate displays the trend of dry-cool〉dry-hot>wet-hot. When the temperature is low, the issolution rate of carbonate is high, and as the drainage condition is good, Ca and Mg released by carbonate dissolution are easy to be discharged from the system. Concerning the acid-insoluble residues in carbonate rocks, firstly, the weathering intensity of arrier minerals of K,Na,Mg, Si and P is the strongest in dry-hot condition (as for Ca, for both calcite and dolomite are its major carrier minerals in carbonate rocks, it is different to effectively identify Ca deriving from acid-insoluble phase in eaching sloution). Between dry-cool and wet-hot, the release ability of K, Na and Mg, i. e. base cations, from the system, in most cases, is for wet-hot>dry-cool, and it is indicated that the temperature severely constrains the release strength of base cations; the release ability of Si and P is not demonstrated a consistent trend in three samples, and it may be caused by the differences in microenvironment of the leaching system. Secondly, Fe and Mn are weak migration elements. Among them,the leaching intensity of Fe in dry-cool condition is the weakest, and it indicates that the temperature is an important factor to constrain the decomposition rate of Feontaining minerals. While leaching intensity of Febetween dry-hot and wet-hot and Mn among three kinds of different leaching conditions,do not show a consistent trend in three samples. Thirdly, A1 and Ti show strong inertness during weathering of carbonate rocks. |
|
来源
|
中国岩溶
,2012,31(4):361-376 【扩展库】
|
|
关键词
|
碳酸盐岩风化壳
;
岩-土界面
;
岩粉层
;
风化作用
;
淋溶模拟
;
贵州
|
|
地址
|
1.
南华大学核资源与核燃料工程学院, 环境地球化学国家重点实验室, 湖南, 衡阳, 421001
2.
南华大学核资源与核燃料工程学院, 湖南, 衡阳, 421001
3.
中国科学院地球化学研究所, 环境地球化学国家重点实验室, 贵州, 贵阳, 550002
|
|
语种
|
中文 |
|
ISSN
|
1001-4810 |
|
学科
|
地质学 |
|
基金
|
国家自然科学基金项目
;
国家基金委创新团队项目
;
中国科学院战略性先导科技专项
|
|
文献收藏号
|
CSCD:4750570
|
参考文献 共
42
共3页
|
|
1.
朱立军. 碳酸盐岩地区红土针铁矿中铝对铁的置换作用及其环境意义.
地质地球化学,1997(1):42-45
|
被引
9
次
|
|
|
|
|
2.
季宏兵.
贵州岩溶台地白云岩上覆红色风化壳的物质来源、形成地球化学过程和古环境重建. 博士学位论文,2000:1-52
|
被引
1
次
|
|
|
|
|
3.
Trudgill S.
Limestone Geomorphology,1985:26-52
|
被引
4
次
|
|
|
|
|
4.
Walter A V. Behaviour of major and trace elements and fractionation of REE under tropical weathering of a typical apatite-rich carbonatite from Brazil.
Earth and Planetary Science Letters,136:591-602
|
被引
15
次
|
|
|
|
|
5.
Xu Z. A review of advances and outstanding issues in research on the forming mechanism of laterite in south China.
Earth Environment,2005,33:29-36
|
被引
2
次
|
|
|
|
|
6.
Zhang X. Soil creeping in the weathering crust of carbonate rocks and underground soil losses in the karst mountain areas of southwest china.
Carbonates Evaporites,2011,26:149-153
|
被引
7
次
|
|
|
|
|
7.
Ji H B. Geochemistry of red residua underlying dolomites in karst terrains of Yunnan-Guizhou Plateau I. The formation of the Pingba profile.
Chemical Geology,2004,203:1-27
|
被引
34
次
|
|
|
|
|
8.
王世杰. 碳酸盐岩风化成土作用的初步研究.
中国科学(D),1999,29(5):441-449
|
被引
202
次
|
|
|
|
|
9.
冯志刚. 酸不溶物对碳酸盐岩风化壳发育程度的影响.
地质学报,2009,83(6):885-893
|
被引
7
次
|
|
|
|
|
10.
孙承兴. 碳酸盐岩风化壳岩-土界面地球化学特征及其形成过程-以贵州花溪灰岩风化壳剖面为例.
矿物学报,2002,22(2):126-132
|
被引
44
次
|
|
|
|
|
11.
Muller J P. Crystal chemistry of kaolinite and Fe-Mn oxides: Relation with formation conditions of low temperature systems.
American Journal of Science,1995,295:1115-1135
|
被引
2
次
|
|
|
|
|
12.
Girard J P. Laser oxygen isotope analysis of weathering goethite from the Iateritic profile of Yaou, French Guiana: Paleoweathering and paleoclimatic implications.
Applied Geochemistry,1997,12:163-174
|
被引
6
次
|
|
|
|
|
13.
Giral S. The oxygen isotope geochemistry of kaolinites from lateritic profiles: implications for pedology and paIeoclimatoIogy.
Chemical Geology,1993,107:237-240
|
被引
2
次
|
|
|
|
|
14.
李景阳. 碳酸盐岩风化壳界面土层的结构和矿物学特征.
中国岩溶,2000,19(4):301-307
|
被引
14
次
|
|
|
|
|
15.
朱立军. 岩溶环境中岩-土界面方解石的表面化学特征及其反应机理.
中国岩溶,1997,16(1):19-23
|
被引
9
次
|
|
|
|
|
16.
李明琴. 用岩-土显微特征示踪碳酸盐岩母岩的成土过程 --以贵阳市大山洞岩-土剖面为例.
地球与环境,2005,33(4):77-82
|
被引
8
次
|
|
|
|
|
17.
Merino E. Terra rossa genesis, implications for karst, and eolian dust: a geodnamic thread.
Journal of Geology,2008,116:62-75
|
被引
6
次
|
|
|
|
|
18.
Wilke B M. Clay mineralology of a soil sequence in slope deposits derived from hauptdolomit (dolomite) in the Bavarian.
Geoderma,1984,32:103-116
|
被引
5
次
|
|
|
|
|
19.
Egli M. Weathering, mineralogical evolution and soil organic matter along a Holocene soil topose-quence developed on carbonate-rich materials.
Geomorphology,2008,97:675-696
|
被引
7
次
|
|
|
|
|
20.
Khan D H. Clay mineral distribution in some rendzinas, red-brown soils and terra rossas on limestones of different geological ages.
Soil Science,1960,90:312-319
|
被引
6
次
|
|
|
|
|
了解气象卫星更多信息，请访问