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取代基对N-羟基邻苯二甲酰亚胺催化环己烷氧化活性的影响
Effect of substituent group of N-hydroxyphthalimide on catalytic activity in cyclohexane oxidation
查看参考文献12篇
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文摘
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合成了一系列吸电子基团和供电子基团取代的N-羟基邻苯二甲酰亚胺(X-NHPI),研究了芳环上的取代基对NHPI在环己烷选择氧化反应中催化活性的影响。结果表明,吸电子基团可以增强NHPI的催化活性,吸电子能力越强,催化活性越高;供电子基团则降低了NHPI的催化活性。 |
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其他语种文摘
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A series of aryl-substituted N-hydroxyphthalimides (X-NHPI) containing both electron-withdrawing groups and electron-donating groups have been synthesized.The effect of substitution in the aromatic ring of N-hydroxyphthalimide on catalytic activity in cyclohexane oxidation has been tested.The results showed that the electron-withdrawing groups enhance the catalytic activity of the NHPI,the electron-withdrawing ability was stronger.On the other hand,the electron-donating groups decrease the catalytic activity of the NHPI. |
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来源
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应用化工
,2012,41(11):1898-1900 【扩展库】
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关键词
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取代
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NHPI
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环己烷
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氧化
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地址
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中国科学院新疆理化技术研究所, 新疆, 乌鲁木齐, 830011
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语种
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中文 |
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ISSN
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1671-3206 |
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学科
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化学工业 |
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基金
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中国科学院西部之光人才培养计划
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文献收藏号
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CSCD:4707570
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参考文献 共
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