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γ-氨丙基三乙氧基硅烷(APTES)与高岭石层间表面羟基的嫁接反应机理
The Grafting of γ-aminopropyltriethoxysilane onto the Interlayer Hydroxyls of Kaolinite

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文摘 采用γ-氨丙基三乙氧基硅烷(APTES)对不同有序度高岭石的层间表面羟基进行嫁接反应。应用XRD、FTIR、热分析、元素分析等表征手段对产物进行分析。结果表明:高岭石经过二甲基亚砜(DMSO)预插层后,可与APTES反应得到嫁接产物。在相同反应温度下,由于不同有序度高岭石中的DMSO插层分子脱嵌速率不同,导致嫁接产物在嫁接程度上具有明显差异:有序度高,其嫁接程度高;反之,则嫁接程度低。
其他语种文摘 The interactions between γ-aminopropyltriethoxysilane (APTES) and kaolinite with different degree of order were investigated. The samples were characterized by using X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric analysis, and elemental analysis. The obtained results suggests that the APTES is grafted onto the interlayer hydroxyls of kaolinite. The diffusion rate of DMSO is faster than the accession rate of APTES in higher-defect kaolinite under the same reaction temperature, leading to different grafted degree.
来源 矿物学报 ,2012,32(4):468-474 【核心库】
关键词 高岭石 ; 有序度 ; 有机硅烷 ; 嫁接
地址

中国科学院广州地球化学研究所, 中国科学院矿物学与成矿学重点实验室, 广东, 广州, 510640

语种 中文
ISSN 1000-4734
学科 地质学;一般工业技术
基金 国家自然科学基金 ;  中国科学院知识创新工程项目
文献收藏号 CSCD:4706349

参考文献 共 16 共1页

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引证文献 3

1 纪阳 高岭石-氨基硅烷插层复合物的制备与表征 硅酸盐学报,2015,43(4):511-518
被引 1

2 纪阳 N-(β-氨乙基)-γ-氨丙基三甲氧基硅烷嫁接高岭石 硅酸盐学报,2015,43(8):1150-1155
被引 2

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