生物柴油副产甘油合成丙烯醇研究
Synthesis of allyl alcohol from glycerol of biodiesel byproduct
查看参考文献11篇
|
文摘
|
以甲酸、生物柴油的副产物甘油为原料合成丙烯醇,考察了投料比、甘油含水量对甲酸转化率和丙烯醇产率的影响。结果表明,n(甘油)∶ n(甲酸)=1∶ 0.6时,甲酸的转化率达到86.7%,丙烯醇收率(以甲酸计)75.0%;同样条件下,m(水)∶ m(甘油)=1∶ 10,甲酸转化率83.3%,产品收率(以甲酸计)73.5%。 |
|
其他语种文摘
|
Allyl alcohol was synthesized from formic acid and glycerol--byproduct of biodiesel.The effects of water content in glycerol and the mole ratio of glycerol to formic acid were tested.The results showed that when the mole ratio of glycerol to formic acid was 1∶ 0.6,conversion of formic acid was 86.7% and yield of allyl alcohol measured by formic acid was 75.0%.And the same condition, the weight ratio of water to glycerol was 1∶ 10, conversion of formic acid was 83.3% and yield of allyl alcohol was 73.5%. |
|
来源
|
应用化工
,2012,41(10):1729-1731 【扩展库】
|
|
关键词
|
生物柴油
;
甘油
;
丙烯醇
;
含水量
|
|
地址
|
1.
中国科学院研究生院, 北京, 100039
2.
中国科学院新疆理化技术研究所, 新疆, 乌鲁木齐, 830011
|
|
语种
|
中文 |
|
ISSN
|
1671-3206 |
|
学科
|
化学;化学工业 |
|
基金
|
新疆维吾尔自治区自然科学基金
|
|
文献收藏号
|
CSCD:4667843
|
参考文献 共
11
共1页
|
|
1.
Arevalo B. The production of biodiesel from blended commercial oil in Mexico: a comparative study.
Journal of the Mexican Chemical Society,2008,52(2):136-139
|
被引
1
次
|
|
|
|
|
2.
Stamenkovic I S. Continuous biodiesel productions: a review.
Hemijska Industrija,2009,63(1):1-10
|
被引
1
次
|
|
|
|
|
3.
Xu Yunzhen. Utilization of high value-added products based on crude glycerol from biodiesel process.
The Chinese Journal of Process Engineering,2008,8(4):695-702
|
被引
1
次
|
|
|
|
|
4.
Stelmachowski M. Utilization of glycerol, a by-product of the transestrification process of vegetable oils: a review.
Ecological Chemistry and Engineering S-Chemia I Inzynieria Ekologiczna S,2011,18(1):9-30
|
被引
1
次
|
|
|
|
|
5.
Pathak K. Catalytic conversion of glycerol to value added liquid products.
Applied Catalysis a-General,2010,372(2):224-238
|
被引
3
次
|
|
|
|
|
6.
崔小明. 丙烯醇及其衍生产品的生产和应用.
氯碱工业,1999(6):22-28
|
被引
1
次
|
|
|
|
|
7.
Boogaerts I.
Production of 1,4-butanediol involves reacting allyl alcohol with carbon monoxide and hydrogen in alcohol solvent in the presence of catalyst system comprising rhodium complex,trialkyl phosphine ligand, and diphosphine ligand:US,7655821-B1,2010
|
被引
1
次
|
|
|
|
|
8.
Zajacek J G.
1,4-Butanediol production from allyl alcohol,Arco Chem Technology Lp:US,6127584-A,2000
|
被引
1
次
|
|
|
|
|
9.
Liu Y. From glycerol to allyl alcohol:iron oxide catalyzed dehydration and consecutive hydrogen transfer.
Chemical Communications,2010,46(8):1238-1240
|
被引
10
次
|
|
|
|
|
10.
Arceo E. An efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol. Mechanistic studies of a formic acid-mediated deoxygenation.
Chem Commun (Camb),2009(23):3357-3359
|
被引
7
次
|
|
|
|
|
11.
Crank G. Derivatives of orthoacids.
Australian Journal of Chemistry,1964,17(12):1385-1391
|
被引
1
次
|
|
|
|
|
了解气象卫星更多信息，请访问