磺酸功能化离子液体催化3-羟基丙酸甲酯酯交换聚合反应
Ester Exchange Polymerization of 3-Hydroxyl Propionic Acid Methyl Ester Catalyzed by SO_3 H-functionalized Ionic Liquids
查看参考文献21篇
|
文摘
|
以磺酸功能化咪唑离子液体为催化剂,以3-羟基丙酸甲酯为原料,采用自身酯交换法合成了具有生物可降解性能的聚羟基脂肪酸酯.系统考察了离子液体种类、反应温度以及聚合反应时间对反应性能的影响,同时采用红外、核磁、热分析等手段对产物进行表征.研究结果表明:阴离子为CF_3SO_3~-的磺酸功能化离子液体在120℃的低温下催化聚合反应所得聚酯M_w可达10 159,收率82.1%;通过水洗方法可有效去除产物中的离子液体催化剂,从而避免催化剂污染产物. |
|
其他语种文摘
|
Employing SO_3H-functionalized ionic liquids as catalysts,the biodegradable poly[3-hydroxypropionic acid](PHP) was obtained by ester exchange polymerization of 3-Hydroxyl propionic acid methyl ester(3-HPM).The effects of various ionic liquids,reaction temperature and reaction time on the polymerization performance were discussed in detail.Meanwhile,the FTIR,NMR and TG-DSC were applied to characterize the products.The PHP with M_w above 1.0×10~4 and yield above 82% could be obtained when catalyzed by under the optimal reaction conditions.In addition,the catalyst in the polymer could be removed completely after washing with water,efficiently avoiding the pollution of the product. |
|
来源
|
分子催化
,2012,26(4):293-299 【核心库】
|
|
关键词
|
磺酸功能化离子液体
;
3-羟基丙酸甲酯
;
聚3-羟基丙酸酯
;
酯交换聚合
|
|
地址
|
中国科学院兰州化学物理研究所, 中国科学院羰基合成与选择氧化国家重点实验室, 甘肃, 兰州, 730000
|
|
语种
|
中文 |
|
ISSN
|
1001-3555 |
|
学科
|
化学;化学工业 |
|
文献收藏号
|
CSCD:4624312
|
参考文献 共
21
共2页
|
|
1.
Lee S Y. Recent advances in polyhydroxyalkanoate production by bacterial fermentation: mini-review.
Int J Biol Macromol,1999,25(1/3):31-36
|
被引
7
次
|
|
|
|
|
2.
郭秀君. 一种新型塑料（PHB）的研究进展和开发前景.
生物工程进展,1997,5:61-68
|
被引
14
次
|
|
|
|
|
3.
Moore T. Chemosynthesis of bioresorbable poly(gamma-butyrolactone) by ring-ope-ning polymerisation: a review.
Biomaterials,2005,26(18):3771-3782
|
被引
5
次
|
|
|
|
|
4.
Moon S I. Melt polycondensation of L-lactic acid with Sn(II) catalysts activated by various proton acids: A direct manufacturing route to high molecular weight poly(L-lactic acid).
J. Polym. Sci., Part A: Polym. Chem.,2000,38(9):1673-1679
|
被引
44
次
|
|
|
|
|
5.
白雁斌.
生物可降解聚乳酸的合成,2006
|
被引
1
次
|
|
|
|
|
6.
Hori Y. A novel biodegradable poly(urethane ester) synthesized from poly(3-hydroxybutyrate) segments.
Macromolecules,1992,25(19):5117-5118
|
被引
2
次
|
|
|
|
|
7.
Hubbs J C.
Composition and process for the production of poly(3-hydroxyalkan-oates): US. 5 563 239,1996
|
被引
1
次
|
|
|
|
|
8.
Qi X H. Catalytic dehydration of fructose into 5-hydroxymethyl--furfural by ion-exchange resin in mixed-aqueous system by microwave heating.
Green Chem,2008,10(7):799-805
|
被引
21
次
|
|
|
|
|
9.
Wang W. Melt polycondensation of L-lactic acid catalyzed by 1,3-dialkyl-imidazolium ionic liquids.
Polym Int,2008,57(6):872-878
|
被引
4
次
|
|
|
|
|
10.
Fu C. Syntheses of high molecular weight alipha-tic polyesters in 1-alkyl-3-methylimidazo-lium ionic li-quids.
Polymer,2008,49(2):461-466
|
被引
2
次
|
|
|
|
|
11.
Xing H B. Novel bronsted acidic ionic liquids for esterifications.
Ind. Eng. Chem. Res,2005,44(11):4147-4150
|
被引
45
次
|
|
|
|
|
12.
Gu Y L. Esterification of aliphatic acids with olefin promoted by Bronsted acidic ionic liquids.
J. Mol. Catal. A: Chem.,2004,212(1/2):71-75
|
被引
23
次
|
|
|
|
|
13.
龙金星. 功能化离子液体在缩醛（酮）反应中催化性能的研究.
分子催化,2008,22(3):199-204
|
被引
5
次
|
|
|
|
|
14.
Gui J Z. Novel Bronsted acidic ionic liquid as efficient and reusable catalyst system for esterification.
Catal. Commun.,2004,5(9):473-477
|
被引
78
次
|
|
|
|
|
15.
Forbes D C. Bronsted acidic ionic liquids: the dependence on water of the fischer esterification of acetic acid and ethanol.
J. Mol. Catal. A: Chem.,2004,214(1):129-132
|
被引
14
次
|
|
|
|
|
16.
Cole A C. Novel bronsted acidic ionic liquids and their use as dual solvent-catalysts.
J. Am. Chem. Soc.,2002,124(21):5962-5963
|
被引
217
次
|
|
|
|
|
17.
Mansoori Y. Synthesis of thermally stable polyamides with pendant 1,3,4-oxadiazole units via direct polycondensation in ionic liquids.
Polym. Bull.,2012,68(1):113-139
|
被引
3
次
|
|
|
|
|
18.
Zhang S. Influence of Bronsted acid ionic liquid structure on hydroxyacid polyesterification.
Green Chem,2011,13(10):2786-2793
|
被引
5
次
|
|
|
|
|
19.
Thomazeau C. Determination of an acidic scale in room temperature ionic liquids.
J. Am. Chem. Soc.,2003,125(18):5264-5265
|
被引
52
次
|
|
|
|
|
20.
Zhao Y. Catalytic amounts of Bronsted acidic ionic liquids promoted esterification: Study of acidity-activity relationship.
Catal. Commun.,2009,10(5):732-736
|
被引
10
次
|
|
|
|
|
了解气象卫星更多信息，请访问