焦化废水中溶解性有机物组分的特征分析
Composition characterization of dissolved organic matters in coking wastewater
查看参考文献20篇
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文摘
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焦化废水是典型的具有复杂有机质的工业废水,其复杂的有机构成制约了水处理的水质达标,且可能对排入水体构成危害.为了探明其溶解性有机物的组成,采用XAD-8大孔树脂将焦化废水中的溶解性有机物分为亲水性组分(HIS)、疏水酸性组分(HOA)、疏水碱性组分(HOB)和疏水中性组分(HON),分析了各组分的溶解性有机物(DOC)、紫外-可见光谱、色度,并采用GC/MS对各组分中有机物进行定性分析.结果表明,焦化废水中的有机物主要为HIS和HOA组分,其DOC含量分别占总DOC的44.3%和32.4%;焦化废水在200—250 nm和300—400 nm范围内有特征吸收峰,且吸收光强度顺序为HIS>HOA>HON>HOB;焦化废水的色度主要由HOA和HON构成,其在525 nm和436 nm处的吸光度分别占焦化废水吸光度的42.9%(HON)、42.1%(HON)和21.4%(HOA)、15.8%(HOA);焦化废水中亲水性物质主要是苯胺、苯酚、喹啉、异喹啉,疏水酸性物质中主要是各种甲基取代的酚类物质,疏水碱性物质主要是各种胺类和含氮杂环化合物,疏水中性物质主要是吲哚及其衍生物. |
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其他语种文摘
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Coking wastewater is the representative wastewater containing various organic pollutants.In order to ascertain the composition,XAD-8 resin was applied to concentrate and isolate the organic compounds in coking wastewater.Dissolved organic matter in coking wastewater was fractionated into four different fractions: hydrophobic acids(HOA),hydrophobic bases(HOB),hydrophobic neutrals(HON) and hydrophilic substances(HIS).Thereafter,the dissolved organic carbon(DOC),ultraviolet-visible(UV) absorption spectroscopy,chroma and the organic component were determined.The DOC values of HIS and HOA showed these two were the main fractions of DOM,comprising 44.3% and 32.4% of the total sample.The characteristic absorption wavelength of coking wastewaater ranged from 200 nm to 250 nm and 300 nm to 400 nm,and the intension order was HIS>HOA>HON>HOB.The chroma of coking wastewater was composed of HOA and HON,and their absorbance at 525 nm and 436 nm contributed 42.9%,42.1% and 21.4%,15.8% of the total.The dominant compounds were aniline,phenol,quinoline and isoquinoline for HIS,various alkyl phenols for HOA,aniline bases and polycyclic nitrogen-containing aromatics for HOB and indole with its ramifications for HON. |
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来源
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环境化学
,2012,31(5):702-707 【核心库】
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关键词
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焦化废水
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溶解性有机物
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紫外-可见光谱分析
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色度
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地址
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中国科学院广州地球化学研究所, 广州, 510640
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语种
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中文 |
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文献类型
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研究性论文 |
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ISSN
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0254-6108 |
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学科
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行业污染、废物处理与综合利用 |
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基金
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国家自然科学基金重点项目
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国家科技支撑计划重点项目
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文献收藏号
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CSCD:4539283
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参考文献 共
20
共1页
|
|
1.
Li Y M. Treatment of coke-plant wastewater by biofilm systems for removal of organic compounds and nitrogen.
Chemosphere,2003,52(6):997-1005
|
被引
55
次
|
|
|
|
|
2.
中华人民共和国国家发展与改革委员会.
焦化行业污染现状及对策建议,2010
|
被引
1
次
|
|
|
|
|
3.
Zhang M. Coke plant wastewater treatment by fixed biofilm system for COD and NH_3-N removal.
Water Res,1998,32(2):519-527
|
被引
64
次
|
|
|
|
|
4.
任源. 生物流化床A/O~2工艺处理焦化废水过程中有机组分的GC/MS分析.
环境科学学报,2006,26(11):1785-1791
|
被引
57
次
|
|
|
|
|
5.
Czaplicka M. Qualitative and quantitative determination of halogenated derivatives in wastewater from coking plant.
J Sep Sci,2003,26:1067-1071
|
被引
4
次
|
|
|
|
|
6.
陈正夫. 焦化废水中多环芳烃的形态分析.
同济大学学报,1995,23(4):473-476
|
被引
5
次
|
|
|
|
|
7.
何苗. 焦化废水中芳香族有机物及杂环化合物活性污泥法处理中的去除特性.
中国给水排水,1997,13(1):14-17
|
被引
35
次
|
|
|
|
|
8.
高连存. 炼钢厂炼焦车间土壤中PAHs的超临界液体萃取色质联用分析方法研究.
环境科学研究,1998,11(1):36-39
|
被引
5
次
|
|
|
|
|
9.
Mehmet K. Probing reactivity of dissolved organic matter for disinfection by-product formation using XAD-8 resin adsorption and ultrafiltration fraction.
Water Res,2002,36(15):3834-3848
|
被引
2
次
|
|
|
|
|
10.
Tao S. Fraction of TOC in water from Yinluan Channel.
Environ Sci,1993,14(1):13-16
|
被引
1
次
|
|
|
|
|
11.
赵风云. 厌氧-缺氧-好氧处理出水中溶解性有机物组分的特征分析.
环境科学学报,2010,30(6):1144-1148
|
被引
3
次
|
|
|
|
|
12.
国家环保局.
水和废水检测分析方法. (第四版),2002
|
被引
1
次
|
|
|
|
|
13.
张世森.
环境监测技术,1992:79-80
|
被引
4
次
|
|
|
|
|
14.
黄君礼.
紫外吸收光谱法及其应用,1992:22-34
|
被引
6
次
|
|
|
|
|
15.
Buffle J.
Complexation Reactions in Aquatic Systems: An Analytical Apporach,1990:692
|
被引
2
次
|
|
|
|
|
16.
Korshin G V. Influence of chlorination on chromophores and fluorophores in humic substances.
Environ Sci Technol,1999,33(8):1207-1212
|
被引
15
次
|
|
|
|
|
17.
Wang L S. Effect of ammonia nitrogen and dissolved organic matter fractions on the genotoxicity of wastewater effluent during chlorine disinfection.
Environ Sci Technol,2007,41(1):160-165
|
被引
32
次
|
|
|
|
|
18.
韦朝海. 焦化废水污染特征及其控制过程与策略分析.
环境科学学报,2007,27(7):1083-1093
|
被引
46
次
|
|
|
|
|
19.
Pauls R E. Distribution and characterization of phenolics in distillates derived from two-stage coal liquefaction.
Energ Fuel,1990,4:236-242
|
被引
12
次
|
|
|
|
|
20.
张伟. A/O/O生物流化床处理焦化废水中酚类组成及降解特性分析.
环境工程学报,2010,4(2):108-113
|
被引
1
次
|
|
|
|
|
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