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新型细晶Ni3Al涂层的制备及其循环氧化行为研究
Processing and cyclic oxidation of a novel fine-grained Ni3Al coating

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李明菲 1 *   彭晓 2   王福会 1  
文摘 为提高γ’-Ni3Al合金氧化膜与基体间的粘结力,采用Ni与Al颗粒(平均粒径为1 um)共电沉积,然后600℃真空退火2 h的方法,在普通粗晶Ni3Al合金上制备了一种平均晶粒尺寸为450 nm,孔隙率为6%的Ni3Al涂层.与普通粗晶Ni3Al合金900℃下的循环氧化行为相比,Ni3Al细晶多孔涂层表面能形成一层粘附性良好的连续Al2O3膜,抗循环氧化性能显著提高,这主要是由于涂层的细晶结构避免了氧化时空位在Al2O3膜/基材界面沉积形成大尺寸孔洞,增加了Al2O3膜/基材界面结合强度.
其他语种文摘 To improve the adherence of the oxide scale formed on a γ’-Ni3Al alloy,a novel Ni3Al fine-grained coating(average grain size: 450 nm) was developed by annealing an electrodeposited Ni-Al composite(average grain size of Ni and Al: 1 um) in a vacuum at 600℃ for 2h.The Ni3Al coating formed from common coarse grains had a homogeneous distribution of fine pores which gave a porosity of 6%.The cyclic oxidation resistance of the coating at 900℃ was greatly increased compared with that of a conventionally coarse-grained Ni3Al alloy(average grain size: 300 um) due to the formation of a continuous and adherent Al2O3 scale.The main reason for the increased scale adhesion lies in that the fine-grained structure improved the strength of the scale/coating interface by preventing the formation of large-sized voids.
来源 哈尔滨工程大学学报 ,2011,32(4):536-540 【扩展库】
DOI 10.3969/j.issn.1006-7043.2011.04.025
关键词 共电沉积 ; 退火 ; Ni3Al ; 孔洞 ; 细晶 ; 循环氧化 ; 氧化膜粘附性
地址

1. 哈尔滨工程大学材料科学与化学工程学院, 腐蚀与防护国家重点实验室, 辽宁, 沈阳, 110016  

2. 中国科学院金属研究所, 腐蚀与防护国家重点实验室, 辽宁, 沈阳, 110016

语种 中文
文献类型 研究性论文
ISSN 1006-7043
学科 金属学与金属工艺
文献收藏号 CSCD:4196334

参考文献 共 12 共1页

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