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温度和水土比对红壤吸附低分子量有机酸的影响
Effects of Temperature and Solution/Soil Ratio on Adsorption of Low Molecular Weight Organic Acids in Red Soil

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喻艳红 1   张桃林 1   李清曼 2   王兴祥 1 *  
文摘 通过一次平衡法考察了温度和水土比对红壤吸附草酸,柠檬酸,酒石酸和苹果酸的影响.结果表明,有机酸的吸附量,最大吸附量(Sm)及吸附亲和力常数(K)均随温度的升高而增加,随着水土比的增加而降低.温度和水土比变化对有机酸吸附的影响程度因有机酸种类而异,影响程度大小与土壤对有机酸的吸附亲和力(K)大小顺序相反.45℃时,土壤对草酸,柠檬酸,酒石酸和苹果酸的吸附量分别是25℃时的1.19,1.22,1.24和1.28倍;100:1水土比条件下,草酸,柠檬酸,酒石酸和苹果酸的吸附量分别较10:1水土比条件下减少了48.3%,54.9%,63.5%和76.1%
其他语种文摘 This research investigated the effects of temperature and solution/soil ratio on the adsorption of oxalic, citric, tartaric and malic acids in red soil by a batch equilibrium method. The results indicated that the adsorption capacity, the maximum adsorption capacity(Sm) and adsorption affinity constant(K) all increased with the increase of temperature, but decreased with the increase of solution/soil ratio. The effects depended on the kinds of organic acids, and the influencing extent was negative to adsorption affinity constant(K).The adsorption capacities of oxalic, citric, tartaric and malic acids at 45℃ was 1.19,1.22,1.24 and 1.28 times higher than those at 25℃, respectively. The adsorption capacities of oxalic, citric, tartaric and malic acids at 100:1 solution/soil reduced by 48.3%,54.9%,63.5% and 76.1% compared to those at 10:1 solution/soil, respectively
来源 土壤 ,2011,43(1):50-55 【核心库】
关键词 红壤 ; 低分子量有机酸 ; 吸附 ; 温度 ; 水土比
地址

1. 中国科学院南京土壤研究所, 南京, 210008  

2. 中国科学院水生生物研究所, 武汉, 430072

语种 中文
文献类型 研究性论文
ISSN 0253-9829
学科 农业基础科学
基金 中国科学院知识创新工程项目
文献收藏号 CSCD:4152627

参考文献 共 23 共2页

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引证文献 5

1 占丽平 低分子量有机酸对红壤和黄褐土K~+吸附动力学的影响 土壤学报,2012,49(6):1147-1157
被引 6

2 花可可 紫色土坡耕地可溶性有机碳径流迁移特征 农业工程学报,2013,29(5):81-88
被引 21

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