甾萜烷和多环芳烃在风化溢油鉴别中的应用研究
Application of identification of weathered spilled oils by terpane, sterane and polycyclic aromatic hydrocarbon
查看参考文献19篇
文摘
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对母质来源、沉积环境和成熟度各异的原油样品进行风化模拟实验, 并对实验产物进行GC-MS分析, 最后对甾烷、萜烷和多环芳烃进行风化溢油鉴定的可行性、原理、常用指标等进行探讨. 结果表明, 不同油中同一甾烷、萜烷和芳烃生物标志化合物比值参数量值间有显著性差异;对相同油的风化和未风化样品而言, 同一萜烷和甾烷比值参数的变异系数通常小于15%;同一烷基化多环芳烃的特征比值参数变异系数为6.51%~17.68%, 而成熟度指标变异系数通常小于8%. 甾萜烷和多环芳烃可以作为风化溢油鉴别的有效指标. |
其他语种文摘
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The products from the simulated weathered experiment of different crude oil are analyzed by GC/MS.The feasibility, principium and efficient index of the serious-weathered oils identification with the recognition of relative distribution patterns and biomarker of terpanes, steranes and aromatic hydrocarbon based on the geochemical feature were discussed. The results show that the diagnostic ratios of such biomarkers showed distinct characteristics of different crude oils. For the weathered crude oils, the coefficient of variability of terpanes and steranes is less than 15%, while the coefficient of variability of diagnostic ratios of alkylated PAHs and aromatic maturity parameters are 6.51% - 17.68% and less 8%, respectively.So terpanes, steranes and PAHs may be used as an effective indicator of the spilled oils. Such work may be particularly useful for accounting for legal liability of peace-breaker. |
来源
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海洋环境科学
,2010,29(3):297-302 【核心库】
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关键词
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风化模拟
;
溢油指纹鉴定
;
甾萜烷
;
芳烃
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地址
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1.
中国科学院烟台海岸带研究所, 山东, 烟台, 264003
2.
鲁东大学地理与规划学院, 山东, 烟台, 264025
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语种
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中文 |
文献类型
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研究性论文 |
ISSN
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1007-6336 |
学科
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环境污染及其防治 |
基金
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国家自然科学基金
;
中国科学院“优秀博士学位论文、院长奖获得者科研启动专项资金”项目
;
中国科学院知识创新工程重要方向项目
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文献收藏号
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CSCD:3916711
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