Estimation of Physico-chemical Properties of Ionic Liquid EPReO_4 Using Surface Tension and Density
查看参考文献22篇
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文摘
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An ionic liquid (IL) EPReO_4 (N-ethylpyridinium rheniumate) was prepared. The density and surface tension values of the IL were determined in the temperature range of 293.15-343.15 K. The ionic volume and surface en-tropy of the IL were estimated by extrapolation, respectively. In terms of Glasser's theory, the standard molar en-tropy and lattice energy of the IL were estimated, respectively. Using Kabo's and Rebelo's methods, the molar en-thalpy values of vaporization of the IL, △_l~gH_m~0 (298 K), at 298 K and, △_l~gH_m~0 (T_b), at hypothetical normal boiling point were estimated, respectively. According to the interstice model, the thermal expansion coefficient of IL EPReO_4 (α) was calculated and compared with experimental value, finding their magnitude order is in good agree-ment by 8.98%. |
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来源
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Chinese Journal of Chemistry
,2010,28(2):179-182 【核心库】
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DOI
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10.1002/cjoc.201090050
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关键词
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ionic liquid
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density
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surface tension
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interstice model
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地址
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Institute of Rare and Scattered Elements Chemistry, College of Chemistry, Liaoning University, Liaoning, Shenyang, 110036
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语种
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英文 |
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文献类型
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研究性论文 |
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ISSN
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1001-604X |
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学科
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化学 |
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基金
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国家自然科学基金
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the Fundation of Education Bureau of Liaoning Prov-ince
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文献收藏号
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CSCD:3828691
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