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三种热喷涂工艺制备NiCr/Cr_3C_2-BaF_2·CaF_2涂层的结构与性能
Microstructure and Properties of NiCr/Cr_3C_2-BaF_2·CaF_2 Coatings Prepared with Three Kinds of Thermal Sprayed Technologies

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黄传兵 1   杜令忠 1   张伟刚 1 *   王璐 2   侯广库 2  
文摘 采用大气等离子喷涂、爆炸喷涂和超音速火焰喷涂三种热喷涂技术制备了NiCr/Cr_3C_2-BaF_2·CaF_2涂层,分析比较了涂层的显微组织、物相组成、孔隙率、硬度、结合强度及其摩擦学性能.结果表明,与大气等离子喷涂相比,超音速火焰喷涂和爆炸喷涂技术制备的涂层具有更高的致密度、硬度和结合强度.采用包覆法制备的粉末进行喷涂,碳化物失碳明显减少,涂层中氧化物含量低.三种NiCr/Cr_3C_2-BaF_2·CaF_2热喷涂涂层的摩擦系数都随着温度的升高而减小,爆炸喷涂和超音速火焰喷涂涂层的摩擦系数比等离子喷涂涂层的摩擦系数更低,耐磨性得到提高.高温下BaF2·CaF2润滑膜的形成均可有效降低三种涂层的摩擦系数,从而降低涂层和对磨球Si3N4的磨损率.
其他语种文摘 Microstructures, composition, porosity, hardness, bonding strength and tribological properties of NiCr/Cr_3C_2-BaF_2·CaF_2 coatings prepared with plasma spraying (APS), detonation spraying (DS) and high velocity oxy-fuel spraying (HVOF) was systematically investigated. The results show that using coated spray powders, the decarburization of carbide, oxidation and ablation are reduced in thermal spray process. The NiCr/Cr_3C_2-BaF_2·CaF_2 coatings deposited by HVOF and detonation spraying have higher density, hardness and bond strength with comparison to plasma spraying. The friction coefficients of three kinds of NiCr/Cr_3C_2-BaF_2·CaF_2 coatings decrease with the increasing temperatures, and the high temperature friction coefficients are significantly lower than that at room temperature. The friction coefficients of HVOF and detonation spraying coatings are lower than plasma spraying coating, and HVOF and detonation spraying coatings show better wear-resistance. The friction coefficients and wear rates of three coatings as well as the wear rates of coupled Si3N4 balls are reduced due to the formation of BaF2·CaF2 lubrication layer at elevated temperatures.
来源 航空材料学报 ,2009,29(6):70-76 【扩展库】
DOI 10.3969/j.issn.1005-5053.2009.6.014
关键词 热喷涂 ; NiCr/Cr_3C_2-BaF_2·CaF_2 ; 微观结构 ; 力学性能 ; 摩擦磨损
地址

1. 中国科学院过程工程研究所, 多相复杂系统国家重点实验室, 北京, 100190  

2. 沈阳黎明航空发动机(集团)有限责任公司, 辽宁, 沈阳, 110043

语种 中文
文献类型 研究性论文
ISSN 1005-5053
学科 金属学与金属工艺
文献收藏号 CSCD:3763875

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引证文献 7

1 董衍林 等离子喷涂Cr_3C_2/MoS_2复合自润滑涂层的摩擦学性能 润滑与密封,2011,36(5):15-19
被引 1

2 赵秋颖 氟化钙对电弧喷涂铁基涂层组织及磨损性能的影响 材料热处理学报,2014,35(3):200-203
被引 1

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