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Effect of additive on corrosion resistance of NiFe_2O_4 ceramics as inert anodes

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文摘 In order to improve the corrosion resistance of NiFe_2O_4 ceramics as inert anode, additive V_2O_5 was added to raw materials NiO and Fe_2O_3. The inert anodes of nickel-ferrite ceramics were prepared by powder metallurgic method and the static corrosion rate in Na_3AlF_6-Al_2O_3 was determined by mass loss measurement. The effect of V_2O_5 on sintering property and corrosion resistance was studied. The results show that V_2O_5 can promote the grain to develop completely and improve sintering property. EDS results show the reaction product Ni_2FeVO_6 distributes along the grain boundary. The corrosion tests show that V_2O_5 is beneficial to improving corrosion resistance remarkably. The reasons that V_2O_5 can improve the corrosion resistance must be V_2O_5 promoting the gains to develop completely and Ni_2FeVO_6 distributes along the grain boundary. The stable structure can control the chemical dissolution of ceramics anode and the reinforced grain boundary can control the grain-boundary corrosion rate.
来源 Transactions of Nonferrous Metals Society of China ,2008,18(2):356-360 【核心库】
DOI 10.1016/s1003-6326(08)60062-x
关键词 NiFe_2O_4 ; inert anode ; additive ; corrosion resistance
地址

1. School of Materials Science and Engineering, China University of Mining and Technology(Xuzhou), Xuzhou, 221008  

2. School of Materials and Metallurgy, Northeastern University, Shenyang, 110004

语种 英文
文献类型 研究性论文
ISSN 1003-6326
学科 矿业工程
基金 Science and Technology Foundation of China University of Mining and Technology, China ;  Postdoctoral Scientific Research Foundation of Jiangsu Province, China
文献收藏号 CSCD:3252039

参考文献 共 14 共1页

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引证文献 7

1 张明霞 氧分压对Cu-NiFe_2O_4金属陶瓷相成份的影响 低温与超导,2009,37(2):72-74
被引 0 次

2 GAN Xue-ping Influence of Yb_2O_3 addition on microstructure and corrosion resistance of 10Cu/(10NiO-NiFe_2O_4) cermets Transactions of Nonferrous Metals Society of China,2009,19(6):1514-1519
被引 2

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