贵州平坝白云岩风化壳稀土超常富集层中稀土赋存状态的研究
Occurrence of REE at REE extra-enriched bed in Pingba dolomite weathering crust, Guizhou Province, China
查看参考文献25篇
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文摘
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以平坝白云岩风化壳剖面为例,主要利用化学连续提取的方法,结合透射电镜的分析,对碳酸盐岩风化壳岩-土界面附近的稀土超常富集层中REE的赋存状态进行了研究,获得了REE在水溶态及可交换态(相态Ⅰ)、碳酸盐结合态及专性吸附态(相态Ⅱ)、非晶质氧化铁锰结合态(相态Ⅲ)、晶质氧化铁锰结合态(相态Ⅳ)、有机质及硫化物结合态(相态Ⅴ)和残渣态(相态Ⅵ)等6种相态的含量及变化规律.结果表明,REE在富集层中主要以专性吸附态、残渣态和有机态为主.风化前缘可溶态稀土所占比例较高,为稀土在风化壳中的迁移、转化提供可能;基岩中原生含磷稀土矿物的风化产生的稀土磷酸盐矿物的聚集导致了残渣态稀土大量存在于风化前缘;此外,由于风化淋溶的不断进行,可溶态的REE在高的pH值条件与剖面中的有机质、铁锰氧化物和粘土矿物共同作用下沉淀、富集,也导致了风化前缘稀土的超常富集. |
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其他语种文摘
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Behavior and fractionation of REE at a REE extra-enriched bed near the soil-rock boundary in Pingba weathering profile have been studied by chemical sequential extraction experiment and TEM observation. REE in the profile was partitioned into six fractions including soluble and exchangeable ( I), carbonate and adsorbed ( II), amorphous Fe-Mn oxide (IH), crystalline Fe-Mn oxide (IV), organics and sulfide (V), and residual (VI). The states I, Y and VI prevail at the REE extra-enriched bed. Acid-soluble REEs are dominant in the weathering frontier, making REEs easy to migrate downwards and transfer into other states (for example, State II) during weathering process. The secondary mineral of rare earth phosphates formed by weathering of primary phosphor-containing mineral in dolomite was found to be accumulated in the weathering frontier and was the major components in the state VI. With the progressive weathering and leaching, the soluble REE leached from the upper profile can co-precipitate with organics, Fe-Mn oxides and clay minerals under the high pH values near soil-rock boundary, leading to the formation of the REE extra-enriched bed at Pingba, Guizhou Province. |
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来源
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地球化学
,2004,33(6):627-633 【核心库】
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关键词
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碳酸盐岩风化壳
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稀土赋存状态
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富集层
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化学连续提取
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贵州省
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地址
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1.
中国科学院地球化学研究所, 环境地球化学国家重点实验室, 贵州, 贵阳, 550002
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华东师范大学, 河口与海岸学国家重点实验室, 上海, 200062
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语种
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中文 |
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文献类型
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研究性论文 |
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ISSN
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0379-1726 |
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学科
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地质学 |
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基金
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中国科学院广州地球化学研究所知识创新工程领域前沿项目
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国家自然科学基金
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中国科学院西部之光人才培养计划
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文献收藏号
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CSCD:1673755
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参考文献 共
25
共2页
|
|
1.
王世杰. 贵州平坝县白云岩风化壳中稀土元素分布特征之初步研究.
地质科学,2001,36(4):474-480
|
被引
18
次
|
|
|
|
|
2.
孙承兴. 碳酸盐岩风化成土过程中REE超常富集及Ce强烈亏损的地球化学机理.
地球化学,2002,31(2):119-128
|
被引
22
次
|
|
|
|
|
3.
Bandfield J F. Apatite replacement and rare earth mobilization.
Clays Clay Miner,1989,37:113-127
|
被引
24
次
|
|
|
|
|
4.
Braun J-J. Cerium anomalies in lateritic profiles[J].
Geochim Cosmochim Acta,1990,54(3):781-795
|
被引
64
次
|
|
|
|
|
5.
Walter A V. Behaviour of major and trace elements and fractionation of REE under tropical weathering of a typical apatite-rich carbonatite from Brazil[J].
Earth Planet Sci Lett,1995,136(3/4):591-602
|
被引
15
次
|
|
|
|
|
6.
Nesbitt H W. Mobility and fractionation of rare earth elements during weathering of a granodiotite[J].
Nature,1979,279:206-210
|
被引
165
次
|
|
|
|
|
7.
雷国良. 贵州岩溶沉积物稀土元素地球化学研究.
矿物学报,1994,14(3):298-308
|
被引
15
次
|
|
|
|
|
8.
林传仙. 风化壳淋积型稀土矿床成矿机理的实验研究.
地球化学,1994,23(2):189-198
|
被引
22
次
|
|
|
|
|
9.
Byrne R H. The limiting role of PO3-4 on dissolved rare earth concentrations in seawater[J].
Geochim Cosmochim Acta,1993,57(3):519-526
|
被引
7
次
|
|
|
|
|
10.
陈志澄. 试论有机质在华南花岗岩风化壳REE溶出、迁移和富集中的作用.
地球化学,1994,23(2):168-178
|
被引
17
次
|
|
|
|
|
11.
陈志澄. 风化壳稀土矿有机成矿机理研究.
中国稀土学报,1997,15(3):244-251
|
被引
13
次
|
|
|
|
|
12.
Nasraoui M. Differentiated hydrothermal and meteoric alterations of the Lueshe carbonatite complex (Democratic Republic of Congo) identified by a REE study combined with a sequential acid-leaching experiment[J].
Chem Geol,2000,165(1/2):109-132
|
被引
1
次
|
|
|
|
|
13.
Sholkovitz E R. The fractionation of rare earth elements between suspended particles and seawater[J].
Geochim Cosmochim Acta,1994,58(6):1567-1579
|
被引
66
次
|
|
|
|
|
14.
Tessier A. Sequential extraction procedure for the speciation of particulate trace metals[J].
Anal Chem,1979,51:844-851
|
被引
1915
次
|
|
|
|
|
15.
Gleyzes C. A review of sequential extraction procedures[J].
Trends Anal Chem,2002,21(6/7):451-467
|
被引
73
次
|
|
|
|
|
16.
Salomons W. Adoption of common schemes for single and sequential extractions of trace-metal in soil and sediments[J].
Int J Environ Anal Chem,1993,51:3-4
|
被引
6
次
|
|
|
|
|
17.
Land M. Solid speciation and fractionation of rare earth elements in a spodosol profile from northern Sweden as revealed by sequential extraction[J].
Chem Geol,1999,160(1/2):121-138
|
被引
9
次
|
|
|
|
|
18.
孙承兴. 碳酸盐岩酸不溶物作为贵州岩溶区红色风化壳主要物质来源的证据.
矿物学报,2002,22(3):235-242
|
被引
30
次
|
|
|
|
|
19.
Bowles J F W. The composition of rhabdophane [J].
Mineral Mag,1984,48:146-148
|
被引
2
次
|
|
|
|
|
20.
Braun J-J. Solid/liquid REE fractionation in the lateritic system of Goyoum.
Geochim Cosmochim Acta,1998,62(2):273-299
|
被引
27
次
|
|
|
|
|
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