土壤和沉积物中重金属积累及其Pb、S同位素示踪
ACCUMULATION OF HEAVY METALS IN SOILS AND SEDIMENTS AND DETERMINATION OF POLLUTANT SOURCE BY Pb AND S ISOTOPIC TRACERS
查看参考文献29篇
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文摘
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对榨子厂附近一个废弃多年的古老土法炼锌点土壤和沉积物中重金属的积累及污染程度进行了研究.研究区土壤、沉积物样品中Pb、Zn、Cd含量已大大高于该地区的背景值,Zn的积累明显大于Pb的积累程度.相关分析表明,土壤和沉积物中FezO3对重金属有强烈的固定作用.沉积物和土壤中有很高的综合污染指数,显示出重金属的污染程度很高.化学形态分析表明重金属以碳酸盐结合态、残渣态和铁锰氧化物结合态为主,有效态所占的比例很低,但其含量并不很低,在酸性条件下,有释放导致污染的可能性.同位素示踪结果显示,研究区土壤和沉积物中积累的Pb、S为矿山物质来源. |
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其他语种文摘
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In the study region, heavy metals in soils and sediments, as observed, greatly exceed the regional background values. Cor-relation analyses revealed high positive correlations between Fe..O,, and heavy metal concentrations, indicating stronger abilities of Fe2O3 to fix heavy metals. Very high CPI values could be figured out for heavy metals in soils and sediments, showing a very high pollution degree of heavy metals. Results of sequential extraction demonstrated that heavy metals were bound mainly to carbonate, iron and manganese oxides, and minerals; only a few exchangeable fractions were extracted. But exchangeable frac-tion metals are high in concentrations, indicating a pollution possibility by heavy metal released under acidic conditions. Pb and S isotopic tracers gave results that heavy metals accumulated in soils and sediments were mainly from mine substances, espe-cially those from local Zn smelting in the region. |
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来源
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地球与环境
,2004,32(1):76-81 【核心库】
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关键词
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重金属
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综合污染指数
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化学形态
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同位素示踪
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地址
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中国科学院地球化学研究所, 贵州, 贵阳, 550002
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语种
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中文 |
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文献类型
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研究性论文 |
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ISSN
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1672-9250 |
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学科
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环境质量评价与环境监测 |
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基金
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中国科学院知识创新工程项目
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文献收藏号
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CSCD:1673323
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参考文献 共
29
共2页
|
|
1.
Little P. A survey of zinc.
Environmental Pollution,1972,3:241-254
|
被引
2
次
|
|
|
|
|
2.
Linzon S N. Lead contamination of urban soils and vegetation by emissions from secondary lead smelters[J].
J. Air Pollut. Control Association,1976,26:650-654
|
被引
1
次
|
|
|
|
|
3.
Harrison M R. Concentration of lead in the atmosphere and soil measured in the vicinity of a secondary lead smelter [J].
Environ. Technol. Lett,1981,2(6):233-242
|
被引
1
次
|
|
|
|
|
4.
Farago M E. Soil and plant concentrations of cadmium and zinc in the vicinity of a smelter[J].
Miner. Environ,1983,5:71-78
|
被引
1
次
|
|
|
|
|
5.
Rieuwerts J. Heavy metal pollution in the vicinity of a secondary lead smelter in the Czech Republic[J].
Applied Geochemistrry,1996,11:17-23
|
被引
2
次
|
|
|
|
|
6.
Verner J F. Heavy metal contamination of soils around a Pb-Zn smelter in Bukowno.
Applied Geochemistry,1996,11:11-16
|
被引
19
次
|
|
|
|
|
7.
Rigina O. Monitoring of forest damage in the Kola Peninsula.
The Science of the Total Environment,1999,229:147-163
|
被引
1
次
|
|
|
|
|
8.
Ullrich S M. Total and exchangeable concentrations of heavy metals in soils near Bytom.
Applied Geochemistry,1999,14:187-196
|
被引
9
次
|
|
|
|
|
9.
Basta N T. Estimation of Cd.
J. Soil Contam,2000,9:149-164
|
被引
7
次
|
|
|
|
|
10.
Li X. Chemical partitioning of trace and major elements in soils contaminated y mining and smelting activities[J].
Applied Geochemistry,2001,16:1693-1706
|
被引
8
次
|
|
|
|
|
11.
Kaasalainen. Use of sequential extraction to assess metal partitioning[J].
Environmental Pollution,2003,126:225-233
|
被引
1
次
|
|
|
|
|
12.
Basta N T. Evaluation of chemical immobilization treatments for reducing heavy metal transport in a smelt r-contaminated soil[J].
Environmental Pollution,2004,127:73-82
|
被引
97
次
|
|
|
|
|
13.
Rolfe G L. Environmental lead distribution in relation to automobile and mine and smelter sources [A].
Heavy Metals in the Aquatic Environment,1975:231-241
|
被引
3
次
|
|
|
|
|
14.
Tessier A. Sequential extraction procedure for the speciation of particulate trace metals[J].
Anal. Chem,1979,51(7):844-851
|
被引
1915
次
|
|
|
|
|
15.
Li X. Sequential extraction of soils for multielement analysis by ICP-AES[J].
Chem. Geol,1995,124:109-123
|
被引
14
次
|
|
|
|
|
16.
Ivask A. Recombinant luminescent bacterial sensors for the measurements of bioavailability of cadmium and lead in soils polluted by metal smelters [J].
Chemosphere,2004,55(2):147-156
|
被引
4
次
|
|
|
|
|
17.
李振纲. c.
贵州六百年经济史,1998:156-166
|
被引
1
次
|
|
|
|
|
18.
Yanagisawa F. Thermal decomposition of barium sulfate-vanadium pentaoxide-silica glass mixtures for preparation of sulfur dioxide in sulfur isotope ratio measurements [J].
Analytical Chemistry,1983,55:985-987
|
被引
15
次
|
|
|
|
|
19.
中国环境监测总站. 中国环境监测总站.
中国土壤元素背景值,1990
|
被引
892
次
|
|
|
|
|
20.
何邵麟. 贵州表生沉积物地球化学背景特征[J].
贵州地质,1998,15(2):149-156
|
被引
24
次
|
|
|
|
|
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