热液中铅、锌、银共生分异的热力学探讨
A THERMODYNAMIC STUDY ON PARAGENESIS AND SEPARATION OF SILVER,LEAD AND ZINCIN HYDROTHERMAL SOLUTIONS
查看参考文献19篇
|
文摘
|
通过元素基本性质的对比以及热力学计算分析,探讨了热液中银、铅、锌的共生分异机制.在酸性至近中性条件下,氯配合物是它们在热液中的存在形式,其中锌氯配合物最稳定;在近中性到碱性条件下,硫氢配合物占主导地位,此时,银硫氢配合物相对最稳定.温度下降、[Cl]降低、pH升高及f(O2)降低,引起银、铅、锌配合物溶解度减小,发生沉淀分离;对于硫氢配合物,其稳定性主要受pH及还原硫浓度的影响.因此,配合物的不同存在形式以及配合物稳定性之间的差异,使得它们对热液条件的改变做出不同的响应,从而导致了热液中银、铅、锌在成矿过程中的共生分异. |
|
其他语种文摘
|
On the basis of the comparison of basic properties and thennodynamic calculation, the mechanism of paragenesis and separation of silver, lead and zinc in the hydrothermal system has been studied. Under acidic to nearly neutral pH conditions, their chloride complexes are stable, and among them chloride complexes of zinc are most stable. Sulfide complexes are the dominant species under nearly neutral to alkaline pH conditions, while the sulfide complexes of silver are most stable. With decreasing temperature, [Cl~-], f(O_2) and increasing pH, the solubilities of silver, lead and zinc will decrease, leading to their deposition and separation. For sulfide complexes, the concentrations of reduced sulfur and pH are two important factors, affecting their stabilities. Differences in form and stability of the complexes respond to the variation of thennodynamic conditions to different extent, which resulted in the paragenisis and separation of silver, lead and zinc in the whole ore-forming process of dissolution, transport and deposition. |
|
来源
|
矿物学报
,2004,24(1):81-86 【核心库】
|
|
关键词
|
铅锌银
;
共生分异
;
热液过程
;
热力学
|
|
地址
|
中国科学院,地球化学研究所, 矿床地球化学开放研究实验室, 贵阳, 550002
|
|
语种
|
中文 |
|
文献类型
|
研究性论文 |
|
ISSN
|
1000-4734 |
|
学科
|
地质学 |
|
基金
|
国家973计划
|
|
文献收藏号
|
CSCD:1501185
|
参考文献 共
19
共1页
|
|
1.
王静纯. 中国银矿[M].
中国银矿,1990:1-390
|
被引
2
次
|
|
|
|
|
2.
涂光炽. 中国层控矿床地球化学(第一卷.
中国层控矿床地球化学,1987:13-69,1-41
|
被引
1
次
|
|
|
|
|
3.
Nriagu J O. stability of lead (Ⅱ) thiocomplexes at 90℃[J].
Chemical Geology,1971,8:299-310
|
被引
7
次
|
|
|
|
|
4.
Nriagu J O. Stability of the lead (Ⅱ) chloride complexes at elevated temperatures[J].
Chemical Gelology,1971,7:171-183
|
被引
8
次
|
|
|
|
|
5.
Anderson G M. The hydrothermal transport and deposition of galena and sphalerite near 100℃[J].
Econ Geol,1973,68:480-492
|
被引
12
次
|
|
|
|
|
6.
Anderson G M. Precipitation of Missippi Valley-type ores[J].
Econ Geol,1975,70:937-942
|
被引
24
次
|
|
|
|
|
7.
Seward T M. a spectrophotometric study [J].
Geochim Cosmochim Acta,1984,48:121-134
|
被引
22
次
|
|
|
|
|
8.
Ruaya J R. The stability of chlorozinc(Ⅱ) complexes in hydrothermal solutions up to 350 ℃[J].
Geochim Cosmochim Acta,1986,50:651-661
|
被引
31
次
|
|
|
|
|
9.
Bourcier W L. Ore Solution Chemistry-Ⅶ.
Econ Geol,1987,82:1839-1863
|
被引
16
次
|
|
|
|
|
10.
Barrett T J. The solubility of sphalerite and galena in 1-5M NaCl solutions to 300 ℃[J].
Geochim Cosmochim Acta,1988,52:813-820
|
被引
9
次
|
|
|
|
|
11.
Seward T M. The stability of chloride complexs of silver in hydrothermal solution up to 350 ℃ [J].
Geochim Cosmochim Acta,1976,40:1329-1341
|
被引
23
次
|
|
|
|
|
12.
Helgeson H C. Thermodynamics of hydrothermal systems at elevated temperatures and pressures[J].
Am J Sci,1969,267:729-804
|
被引
34
次
|
|
|
|
|
13.
Gammons C H. The solubility of Ag2S in near-neutral aqueous sulfide solutions at 25-300 ℃[J].
Geochim Cosmochim Acta,1989,53:279-290
|
被引
24
次
|
|
|
|
|
14.
Barnes H L. Geochemistry of Hydrothermal Ore Deposits [M].
Geochemistry of Hydrothermal Ore Deposits,1997
|
被引
6
次
|
|
|
|
|
15.
Johnson J W. A software package for calculating the standard molar aqueous species and reactions from 1 to 5000 bar and 0 to 1000℃ [J].
Computer and Geoscience,1992,18:899-947
|
被引
48
次
|
|
|
|
|
16.
Seccombe P K. Experimental mobility of sulfides along hydrothermal gradients[J].
Econ Geol,1990,85:1099-1113
|
被引
1
次
|
|
|
|
|
17.
尚林波. 热液中银、铅、锌共生分异的实验研究.
矿物学报,2003,23(1):31-35
|
被引
21
次
|
|
|
|
|
18.
Wood S A. Solubility of the assemblage pyrite-pyrrhotite-magnetite-sphalerite-galena-gold-stibnite-bismuthinite-argentite-molybdenite in H2O-NaCl-CO2 solutions from 200 ℃ to 300 ℃ [J].
Econ Geol,1987,82:1864-1887
|
被引
23
次
|
|
|
|
|
19.
张德会. 成矿流体中金属沉淀机制研究综述 [J].
地质科技情报,1997,16(3):53-58
|
被引
39
次
|
|
|
|
|
了解气象卫星更多信息，请访问