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Cr含量对CrMnFeNi系高熵合金腐蚀行为的影响
Effect of Cr content on corrosion behavior of CrMnFeNi high entropy alloys

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文摘 利用XRD,SEM/EDS,EBSD,电化学测试等表征手段研究Cr含量对Cr_xMnFeNi(x=0.8,1.0,1.2,1.5)高熵合金微观组织与耐蚀性能的影响。结果表明:Cr_(0.8)MnFeNi高熵合金为单相FCC结构,Cr_xMnFeNi(x= 1.0,1.2,1.5)高熵合金为FCC+BCC双相结构,且BCC相比例随着Cr含量升高而增加。在0.5 mol/L H_2SO_4溶液中,高熵合金的耐蚀性能随着Cr含量降低而增强,其中,Cr_(0.8)MnFeNi单相高熵合金的耐蚀性能最好,这是因为Cr_(0.8)MnFeNi高熵合金的成分更为均匀。此外,Cr_xMnFeNi高熵合金在0.5 mol/L H_2SO_4溶液中均具有宽泛的钝化区域以及明显的伪钝化区域,表明合金在耐蚀性能上具有较大的研究价值和开发潜力。
其他语种文摘 The effect of Cr content on the microstructure and corrosion resistance of Crx MnFeNi (x = 0.8,1.0,1.2,1.5) high entropy alloys was studied by using XRD, SEM/EDS, EBSD and electrochemical testing. The results show that Cr_(0.8)MnFeNi high entropy alloy exhibits single FCC phase structure, while Cr_xMnFeNi(x= 1.0,1.2,1.5) high entropy alloys show FCC+BCC dual phase structure,and the BCC phase ratio of dual phase alloys increases with the increase of Cr content. The corrosion resistance of high entropy alloys gradually increases with the decrease of Cr content. Among them,Cr_(0.8)MnFeNi high entropy alloy has the best corrosion resistance,because the composition of the alloy is more uniform. In addition, Crx MnFeNi high entropy alloys have extensive passive region and obvious pseudo passive region in 0.5 mol/L H_2SO_4 solution, which indicates the alloys have greater research value and development potential in corrosion resistance.
来源 材料工程 ,2022,50(11):127-134 【核心库】
DOI 10.11868/j.issn.1001-4381.2021.000431
关键词 Cr含量 ; 高熵合金 ; 组织结构 ; 电化学测试 ; 耐蚀性能
地址

北京科技大学, 钢铁共性技术协同创新中心, 北京, 100083

语种 中文
文献类型 研究性论文
ISSN 1001-4381
学科 金属学与金属工艺
文献收藏号 CSCD:7398766

参考文献 共 19 共1页

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引证文献 4

1 刘云帆 金属材料在超临界水中动态腐蚀特性 材料工程,2023,51(11):61-70
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2 于秋颖 高熵合金热变形行为研究进展 材料工程,2024,52(1):45-56
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