含能材料合成中的氮链扩增方法
Amplification Methods of Nitrogen Chains in the Synthesis of Energetic Materials
查看参考文献64篇
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文摘
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综述了含能材料合成中的氮链扩增化学反应方法,总结了氮-卤键的叠氮化取代、叠氮离子的电催化氧化、伯胺重氮转移、二氮烯的二聚、N氨基化及硝化、氨基氧化偶联、氨基重氮偶联等共性反应,介绍了典型氮链扩增反应的机理。重点讨论了N_5~+、[N_7O]~+、N_8~-等离子型氮链,以及具有N_3/N_4/N_5/N_6/N_7/N_8/N_(10)/N_(11)链等全氮片段的有机化合物的结构演进过程,提出了N_7~- 、N_(10)、N_(12)长氮链化合物的可能合成路线,最后提出了该领域后续发展的趋势和建议。附参考文献65篇。 |
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其他语种文摘
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The developments of amplification methods of nitrogen chains in energetic material synthesis were reviewed. The common reactions such as substitution reactions of N-X bonds by azido groups,electro-catalytic oxidation reactions of azide ions,diazo transfer reactions of primary amines,dimerization reactions of diimine,N-amination and nitration reactions,oxidative coupling reactions of amine groups,and diazo-coupling reactions of amine groups were summarized.The mechanisms of typical amplification reactions of nitrogen chains were also introduced.The structural evolution processes of ionic nitrogen chains such as N_5~+,[N_7O]~+,N_8~-,and organic compounds with all-nitrogen fragments such as N_3/N_4/N_5/N_6/N_7/N_8/N_(10)/N_(11) chains were emphatically discussed.The possible synthetic routes of N_7~-,N_(10) and N_(12) chains and the development trends of this research field were pointed out.With 65 references. |
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来源
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火炸药学报
,2021,44(1):21-29 【核心库】
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DOI
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10.14077/j.issn.1007-7812.201911017
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关键词
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有机化学
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氮链扩增方法
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全氮材料
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N5
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N8
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N10
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N11
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地址
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1.
西安近代化学研究所, 陕西, 西安, 710065
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氟氮化工资源高效开发与利用国家重点实验室, 氟氮化工资源高效开发与利用国家重点实验室, 陕西, 西安, 710065
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中国兵器科学研究院, 北京, 100089
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语种
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中文 |
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文献类型
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研究性论文 |
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ISSN
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1007-7812 |
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学科
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化学;武器工业 |
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基金
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国家自然科学基金
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文献收藏号
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CSCD:6920064
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