FeCrNiMo激光熔覆层组织与电化学腐蚀行为研究
Microstructure and Electrochemical Corrosion Behavior of FeCrNiMo Layer Fabricated by Laser Cladding
查看参考文献28篇
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文摘
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目的研究所设计FeCrNiMo激光熔覆层的组织结构及电化学腐蚀行为,用于解决液压支架表面防护与修复问题。方法采用激光熔覆技术在27SiMn钢表面制备FeCrNiMo合金熔覆层,通过XRD、光学显微镜和SEM表征其微观组织结构,利用动电位极化与交流阻抗谱技术研究熔覆层电化学腐蚀行为。结果在适宜工艺条件下实现了单道熔覆层厚度达2 mm以上,且无明显气孔、裂纹等缺陷。熔覆层具有胞状枝晶组织特征,枝晶内为马氏体,晶间富Cr、Mo的铁素体有效缓解了马氏体相变的高应力,达到了较好的强韧化匹配。熔覆层在3.5%NaCl和0.5 mol/L H_2SO_4溶液中均呈现出明显的钝化行为,钝化区间宽度分别为300 mV和1310 mV,自腐蚀电位分别为–140.2 mV和2.3 mV,自腐蚀电流密度分别为5.0×10~(–8)A/cm~2和1.3×10~(–3) A/cm~2,极化电阻分别为3.5×10~5 Ω·cm~2和6261.4 Ω·cm~2,具有较为优异的耐腐蚀性能,且显著优于基体材料,但其双相组织特征易导致微区发生选择性腐蚀。结论所设计的FeCrNiMo合金及相应激光熔覆工艺,满足实际工程对于熔覆层高效制备、成形质量及耐蚀性的要求,可用于液压支架表面防护与修复。 |
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其他语种文摘
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The work aims to study the microstructure and electrochemical corrosion behavior of FeCrNiMo laser cladding layer, so as to solve the problems of hydraulic support surface protection and repair. FeNiCrMo alloy layer was prepared on 27SiMn steel substrate by laser cladding, and the microstructure and electrochemical corrosion behavior of this layer were investigated by XRD, optical microscope, SEM, potentiodynamic polarization and electrochemical impedance spectroscopy. Under optimized processing parameters, the layer had a single-cladding thickness of over 2 mm, without obvious defects like pores, cracks. The cladding layer presented a cellular dendritic structure involving martensite in dendrite and intergranular Cr/Mo-rich ferrite, thus achieving a good balance of strengthening and toughening. The cladding layer exhibited obvious passivation behavior in both 3.5wt% NaCl and 0.5 mol/L H_2SO_4 solutions. The passive region had a width of 300 mV and 1310 mV, the corrosion potential was detected to be –140.2 mV and 2.3 mV, the corrosion current density was measured as 5.0×10~(–8) A/cm~2 and 1.3×10~(–3) A/cm~2, and the polarization resistance was calculated to be 3.5×10~5 Ω·cm~2 and 6261.4 Ω·cm~2, respectively. This cladding layer depicted excellent corrosion resistance that was superior to the substrate, although selective corrosion occurred in micro-area due to duplex phase structure. Therefore, the designed FeNiCrMo alloy and related laser cladding parameters satisfy the engineering demands for processing efficiency and performance and can be used for protecting and repairing hydraulic supports. |
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来源
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表面技术
,2020,49(12):228-234 【核心库】
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DOI
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10.16490/j.cnki.issn.1001-3660.2020.12.026
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关键词
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激光熔覆
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FeCrNiMo合金
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微观组织
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动电位极化
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交流阻抗谱
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地址
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北京工业大学材料与制造学部, 北京, 100124
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矿冶科技集团有限公司, 北京, 100160
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中国科学院金属研究所, 沈阳, 110016
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语种
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中文 |
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文献类型
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研究性论文 |
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ISSN
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1001-3660 |
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学科
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金属学与金属工艺 |
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基金
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国家重点研发计划项目
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文献收藏号
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CSCD:6884596
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