高性能锂离子二次电池隔膜
High-Performance Lithium-Ion Secondary Battery Membranes
查看参考文献115篇
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文摘
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随着电动汽车对锂离子电池功率要求的不断提高,高性能锂离子电池逐渐成为了人们研究的热点。隔膜作为锂离子电池的关键部件之一,发挥着隔离正负极材料以及为锂离子迁移提供通道的作用。此外,隔膜的热稳定性也直接影响着锂离子电池的安全性能。聚烯烃微孔隔膜由于其出色的化学稳定性、机械强度以及价格低廉而被广泛应用于锂离子电池中。然而,其热稳定性差以及不易湿润等缺点给高性能锂离子电池的广泛应用带来很大隐患。因此,本文探讨了聚烯烃微孔隔膜的表面改性,以此为出发点,介绍了基于聚合物表面改性的聚烯烃微孔隔膜、基于无机纳米颗粒的聚烯烃微孔隔膜、基于有机-无机复合材料的聚烯烃微孔隔膜的研究进展。在基于无机纳米颗粒的聚烯烃微孔隔膜的介绍中,本文还对原子层沉积法、化学气相沉积法、物理气相沉积法等先进表面改性方法进行了简单介绍。随后,从湿法制备、相转化法、呼吸图法、静电纺丝法以及原位聚合法5种方法出发,对其他聚合物微孔隔膜的研究进展进行了介绍。最后,本文对将来高性能隔膜材料的研究方向上作出展望,旨在为高性能锂离子二次电池隔膜材料的研究和应用提供参考。 |
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其他语种文摘
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With the continuous improvement of the requirements for the power of lithium-ion batteries in electrical vehicles,high-performance lithium-ion batteries are becoming the focus of researchers.As one of the critical components in lithium-ion batteries,membranes play the role of separating the anode and cathode materials and providing the channels for lithium ions to translate.In addition,the thermal stability of membranes can affect the safety of batteries directly.Polyolefin microporous membranes are widely used in lithium batteries for their excellent chemical stability,high mechanical strengths and low cost.However,the poor thermal stability and wettability bring great hidden danger to the wide application of high-performance lithium-ion batteries.As a result,starting from the surface modification of polyolefin microporous membranes,the paper introduces the research progress of polyolefin microporous membranes which are based on polymer surface modification and inorganic nanoparticles,organic-inorganic composites.When introducing the polyolefin microporous membranes based on inorganic nanoparticles,the paper makes a brief introduction to those advanced surface modification methods such as atomic deposition,the chemical vapor deposition method and the physical vapor deposition method.Subsequently,based on the shortcomings of polyolefin,the research progress of other polymer microporous membranes are introduced with respect to the wet process,the phase inversion method,the breath figure method,electrospinning and the in-situ polymerization.At last,the paper makes an outlook for the future researches of high-performance membranes and means to provide a reference for the research and application of high-performance membranes in lithium-ion secondary battery membranes. |
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来源
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化学进展
,2019,31(9):1251-1262 【核心库】
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DOI
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10.7536/pc190304
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关键词
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锂离子二次电池
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隔膜材料
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表面改性
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聚烯烃隔膜
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原位聚合
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地址
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1.
上海交通大学材料科学与工程学院, 上海, 200240
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纳米技术及应用国家工程研究中心, 纳米技术及应用国家工程研究中心, 上海, 200241
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语种
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中文 |
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文献类型
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综述型 |
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ISSN
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1005-281X |
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学科
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化学;电工技术 |
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基金
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国家973计划
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上海市基础重大项目
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文献收藏号
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CSCD:6570272
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