In-situ Synthesis of Perovskite SrTiO_3 Nanostructures with Modified Morphology and Tunable Optical Absorption Property
形貌可控及光学吸收性能可调的钙钛矿型SrTiO_3纳米结构的原位生长
查看参考文献35篇
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文摘
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As a perovskite family member, SrTiO_3 shows significant applications in the fields of solar cells, photocatalysis, fuel cells and superconducting as a dependence of its crystallinity, morphology, crystal facet and optical properties. In this work, we reported an in-situ synthetic approach of SrTiO_3 nanostructures with modified morphology and tunable optical absorption properties based on conventional plasma electrolytic oxidation (PEO) associated with hydrothermal method. The morphology of SrTiO_3 nanostructures can be selectively modified from microcubes with smooth facets to ultrathin nanosheets by controlling the concentration of Sr source during PEO process. It is found that both SrTiO_3 microcubes and Sr_(1-δ)TiO_3 nanosheets are well-crystallized single crystals. UV-Vis diffuse reactance spectrum (DRS) measurement reveals that Sr_(1-δ)TiO_3 nanosheets with thin thickness show obvious blue-shift of absorption edge in comparison with SrTiO_3 microcubes due to the size effect. Finally, the morphology evolution and nucleation mechanism of SrTiO_3 nanostructures in-situ grown on PEO film is discussed. |
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其他语种文摘
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钙钛矿相SrTiO_3在太阳能电池、光催化、燃料电池,超导等领域均有广泛应用,这些应用均与其晶体质量、形貌、暴露晶面和光学吸收等特性息息相关。本文通过微弧氧化-水热两步法原位制备了两种典型形貌的SrTiO_3纳米晶。结果表明,随着微弧氧化电解液锶源浓度的降低, SrTiO_3形貌从立方块状转变为超薄片状。进一步分析表明,所得的SrTiO_3立方块和Sr_(1-δ)TiO_3纳米片均为结晶质量良好的单晶体,通过分析两种形貌样品的紫外-可见漫反射光谱,发现Sr_(1-δ)TiO_3纳米片相对于SrTiO_3立方块,具有明显的尺寸效应诱导的光学吸收蓝移特性。最后,本研究提出了SrTiO_3的原位生长及形貌演变机制。 |
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来源
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无机材料学报
,2019,34(1):65-71 【核心库】
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DOI
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10.15541/jim20180255
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关键词
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SrTiO_3
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in-situ growth
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plasma electrolytic oxidation
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morphology tuning
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optical property
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地址
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1.
Institute of Metal Research, Chinese Academy of Sciences, Shenyang National Laboratory for Materials Science, Shenyang, 110016
2.
School of Materials Science and Engineering, University of Science and Technology of China, Hefei, 230026
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语种
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英文 |
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文献类型
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研究性论文 |
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ISSN
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1000-324X |
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学科
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化学工业 |
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基金
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国家自然科学基金
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Knowledge Innovation Program of Institute of Metal Research, Chinese Academy of Sciences
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Youth Innovation Promotion Association, Chinese Academy of Sciences
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Basic Science Innovation Program of Shenyang National Laboratory for Materials Science
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文献收藏号
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CSCD:6430211
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参考文献 共
35
共2页
|
|
1.
Kazim S. Perovskite as light harvester: a game changer in photovoltaics.
Angew Chem. Int. Edit,2014,53(11):2812-2824
|
CSCD被引
48
次
|
|
|
|
|
2.
Sulaeman U. Solvothermal synthesis and photocatalytic properties of chromium-doped SrTiO_3 nanoparticles.
Appl Catal B-Environ,2011,105(1/2):206-210
|
CSCD被引
7
次
|
|
|
|
|
3.
Iwashina K. Rh-doped SrTiO_3 photocatalyst electrode showing cathodic photocurrent for water splitting under visible-light irradiation.
J. Am. Chem. Soc,2011,133(34):13272-13275
|
CSCD被引
25
次
|
|
|
|
|
4.
Comes R B. Visible light carrier generation in co-doped epitaxial titanate films.
Appl. Phys. Lett,2015,106(9):092901-1-092901-5
|
CSCD被引
1
次
|
|
|
|
|
5.
Park K I. Piezoelectric BaTiO_3 thin film nanogenerator on plastic substrates.
Nano Letters,2010,10(12):4939-4943
|
CSCD被引
25
次
|
|
|
|
|
6.
Grabowska E. Selected perovskite oxides: characterization, preparation and photocatalytic properties-a review.
Applied Catalysis B: Environmental,2016,186:97-126
|
CSCD被引
35
次
|
|
|
|
|
7.
Madhavan B. Review on nanoperovskites: materials, synthesis, and applications for proton and oxide ion conductivity.
Ionics,2014,21(3):1-10
|
CSCD被引
1
次
|
|
|
|
|
8.
Kudo A. Heterogeneous photocatalyst materials for water splitting.
Chemical Society Reviews,2009,38(1):253-278
|
CSCD被引
450
次
|
|
|
|
|
9.
Diamant Y. Core-shell nanoporous electrode for dye sensitized solar cells: the effect of the SrTiO_3 shell on the electronic properties of the TiO_2 core.
J. Phys. Chem. B,2003,107(9):1977-1981
|
CSCD被引
27
次
|
|
|
|
|
10.
Lenzmann F. Surface photovoltage spectroscopy of dye-sensitized solar cells with TiO_2, Nb_2O_5, and SrTiO_3 nanocrystalline photoanodes: indication for electron injection from higher excited dye states.
J. Phys. Chem. B,2001,105(27):6347-6352
|
CSCD被引
19
次
|
|
|
|
|
11.
Kang Q. Photocatalytic reduction of carbon dioxide by hydrous hydrazine over Au-Cu alloy nanoparticles supported on SrTiO/TiO coaxial nanotube arrays.
Angewandte Chemie International Edition,2014,54(3):841-845
|
CSCD被引
21
次
|
|
|
|
|
12.
Cao T. A facile in situ hydrothermal method to SrTiO_3/TiO_2 nanofiber heterostructures with high photocatalytic activity.
Langmuir,2011,27(6):2946-2952
|
CSCD被引
30
次
|
|
|
|
|
13.
Long Z. Preparation of SrTiO_3 cubes by molten salt method and its surface ions modification with Cu(II) clusters.
J. Inorg. Mater,2013,28(10):1103-1107
|
CSCD被引
1
次
|
|
|
|
|
14.
Zhu Y R. Preparation and photocatalytic hydrogen generation activity of nitrogen doped SrTiO_3 under visible light irradiation.
J. Inorg. Mater,2008,23(3):443-448
|
CSCD被引
1
次
|
|
|
|
|
15.
Ji L. A silicon-based photocathode for water reduction with an epitaxial SrTiO_3 protection layer and a nanostructured catalyst.
Nat. Nano,2014,10(1):84-90
|
CSCD被引
27
次
|
|
|
|
|
16.
Yan J H. Preparation and photocatalytic hydrogen production of NiO(CoO)/N-SrTiO_3 heterojunction complex catalyst under simulated sunlight irradiation.
J. Inorg. Mater,2009,24(4):666-670
|
CSCD被引
5
次
|
|
|
|
|
17.
Kovalevsky A V. Design of SrTiO_3-based thermoelectrics by tungsten substitution.
The Journal of Physical Chemistry C,2015,119(9):4466-4478
|
CSCD被引
3
次
|
|
|
|
|
18.
Ohtomo A. A high-mobility electron gas at the LaAlO_3/SrTiO_3 heterointerface.
Nature,2004,427(6973):423-426
|
CSCD被引
123
次
|
|
|
|
|
19.
Kuang Q. Template synthesis of single-crystal-like porous SrTiO_3 nanocube assemblies and their enhanced photocatalytic hydrogen evolution.
ACS Applied Materials & Interfaces,2013,5(9):3683-3690
|
CSCD被引
9
次
|
|
|
|
|
20.
Zhan H. Correlation between multiple growth stages and photocatalysis of SrTiO_3 nanocrystals.
The Journal of Physical Chemistry C,2015,119(7):3530-3537
|
CSCD被引
3
次
|
|
|
|
|
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