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Effect of nitrogen on corrosion behaviour of a novel high nitrogen medium-entropy alloy CrCoNiN manufactured by pressurized metallurgy

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文摘 A novel high nitrogen medium-entropy alloy CrCoNiN, which had higher strength and slightly lower ductility than CrCoNi alloy, was successfully manufactured by pressurized metallurgy. The microstructure and corrosion behaviour were investigated by microscopic, electrochemical and spectroscopic methods. The results indicated that nitrogen existed in the form of Cr_2 N precipitates and uniformly distributed N atoms, and nitrogen alloying significantly refined the grain size. Besides, nitrogen enriched on the outmost surface of passive film and metal/film interface as ammonia (NH_3 and NH_4~+) and CrN, respectively. The significant improvement of corrosion resistance of CrCoNiN was attributed to the lower metastable pitting susceptibility together with thicker, less defective and more compact passive film.
来源 Journal of Materials Science & Technology ,2018,34(10):1781-1790 【核心库】
DOI 10.1016/j.jmst.2018.03.021
关键词 Medium-entropy alloy ; Nitrogen ; Pitting corrosion ; Passive film ; Metastable pitting
地址

1. School of Metallurgy, Northeastern University, Shenyang, 110819  

2. Institute of Mechanics, Chinese Academy of Sciences, State Key Laboratory of Nonlinear Mechanics, Beijing, 100190  

3. School of Materials Science and Engineering, Northeastern University, Shenyang, 110819

语种 英文
文献类型 研究性论文
ISSN 1005-0302
学科 金属学与金属工艺
基金 国家自然科学基金 ;  the Transformation Project of Major Scientific and Technological Achievements in Shenyang
文献收藏号 CSCD:6335108

参考文献 共 64 共4页

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引证文献 20

1 Qin Gang Strengthening FCC-CoCrFeMnNi high entropy alloys by Mo addition Journal of Materials Science & Technology,2019,35(4):578-583
CSCD被引 31

2 Jiao Weichao Effect of partial replacement of carbon by nitrogen on intergranular corrosion behavior of high nitrogen martensitic stainless steels Journal of Materials Science & Technology,2019,35(10):2357-2364
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