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Selective recognition of aromatic hydrocarbons by endo-functionalized molecular tubes via C/N-H…π interactions

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Huang Guobao 1,2,3   Liu Weier 3   Valkonen Arto 4   Yao Huan 3   Rissanen Kari 4   Jiang Wei 3 *  
文摘 Molecular recognition of aromatic hydrocarbons by four endo-functionalized molecular tubes has been studied by ~1H NMR spectroscopy, computational methods, and single crystal X-ray crystallography. The binding selectivity is rationalized by invoking shape complementarity and dipole alignment. The non-covalent interactions are proved to predominantly be C/N-H…π interactions. Published by Elsevier B.V. All rights reserved.
来源 Chinese Chemical Letters ,2018,29(1):91-94 【核心库】
DOI 10.1016/j.cclet.2017.07.005
关键词 Macrocycles ; Aromatic hydrocarbon ; Molecular recognition ; Host-guest chemistry ; Hydrogen bond
地址

1. College of Chemistry and Food Science, Yulin Normal University, Yulin, 537000  

2. College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, 518060  

3. Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055  

4. Department of Chemistry and Nanoscience Center, University of Jyvaskyla, Finland, Jyvaskyla, 3540014

语种 英文
文献类型 研究性论文
ISSN 1001-8417
学科 化学
基金 financially supported by the National Natural Science Foundation of China ;  Thousand Young Talents Program, South University of Science and Technology of China ;  the Shenzhen special funds for the development of biomedicine, internet, new energy, and new material industries ;  the Startup Program of Yulin Normal University ;  the Academy of Finland
文献收藏号 CSCD:6162354

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引证文献 9 篇

1 Hu Xiaoyu Virtual special issue: Supramolecular/macrocyclic chemistry Chinese Chemical Letters,2018,29(12):1703-1705
CSCD被引 0 次

2 Xiao Tangxin Dynamic materials fabricated from water soluble pillar[n]arenes bearing triethylene oxide groups Chinese Chemical Letters,2019,30(2):271-276
CSCD被引 5 次

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