Synthesis,Structure and Magnetic Analysis of the Cobalt Polymer Based on N-[(3-pyridine)-sulfonyl] aspartate
查看参考文献20篇
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文摘
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One new cobalt polymer [Co(L)·3H_2O]_n (1,H_2L = N-[(3-pyridine)-sulfonyl]as-partate) has been synthesized and characterized by single-crystal X-ray diffraction and elemental analysis. Polymer 1 belongs to the monoclinic system, space group P2_1/n with a = 11.479(2), b = 7.3180(15), c= 16.424(3) A,β= 109.56(3)°,V= 1300.1(5)A~3, M_r = 385.22, Z= 12,F(000) = 790,S = 1.054,R = 0.0670,wR = 0.1147,(Ap)_(max) = 1.158 and (?p)min= -0.754 e/A~3. TGA showed that the polymer first lost one coordinated water molecule and then another two coordinated water molecules. The values of the Curie and Curie-Weiss constants of polymer 1 are C_m = 2.67 cm~3 mol~(-1) K and θ = -21.66 K. |
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来源
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Chinese Journal of Structural Chemistry
,2017,36(2):266-272 【核心库】
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DOI
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10.14102/j.cnki.0254-5861.2011-1285
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关键词
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polymer
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structure
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magnetic
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N-[(3-pyridine)-sulfonyl]aspartate
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地址
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1.
Military Hospitals of 93307st, Chinese People's Liberation Army, Shenyang, 110141
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College of Chemistry and Pharmacy, Guangxi Normal University, Guilin, 541004
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语种
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英文 |
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文献类型
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研究性论文 |
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ISSN
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0254-5861 |
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学科
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化学 |
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基金
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Supported by the Natural Science Foundation of Guangxi Province
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the Education Department of Guangxi Province
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文献收藏号
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CSCD:5924371
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引证文献
1
篇
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1
Liao Beiling
Syntheses, Structures and Magnetic Analysis of Co(Ⅱ)Coordination Polymer Based on N-(Pyridine-3-sulfonyl amino) Acetate
无机化学学报,2017,33(10):1843-1848
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