渝东漆辽剖面五峰组-龙马溪组页岩及残余干酪根中微量元素地球化学特征
Geochemical Characteristics of Trace Elements of Shales and Their Residual Kerogens from Wufeng-Longmaxi Formations in the Qiliao Section,Eastern Chongqing,China
查看参考文献31篇
文摘
|
为探讨渝东漆辽剖面五峰组-龙马溪组页岩及残余干酪根内部微量金属元素的赋存规律及其对页岩气生成的影响,对页岩及残余干酪根中的微量元素进行了分析测试。结果表明,多数微量金属元素在五峰组-龙马溪组页岩干酪根中较页岩中更为富集,稀土元素表现出轻稀土富集,重稀土亏损,明显Eu负异常,轻微Ce负异常的特征; 说明漆辽剖面五峰组-龙马溪组页岩沉积水体为贫氧-缺氧的热水沉积环境,而热水沉积环境正是导致页岩中V、Ni、U高度富集的原因。 |
其他语种文摘
|
In order to investigate the effect on shale gas generation by trace metal elements in shales and their residual kerogens, geochemical characteristics of trace elements shales and their residual kerogens from Upper Ordovician Wufeng and Lower Silurian Longmaxi formations in the Qiliao Section,Eastern Chongqing have been studied in this paper. Results show that most trace metal elements are more enriched in kerogens than in their host shales from Wufeng and Longmaxi formations. REE of shales and their residual kerogens are characterized with the enrichment of LREE and depletion of HREE,with obvious Eu negative anomaly and a slight Ce negative anomaly in their REE patterns. Overall,it is believed that shales of the Wufeng and Longmaxi formations in the Qiliao section was deposited in a weak oxygen depleted or anoxic hot water environment which caused the high enrichment of V,Ni,U in shales. |
来源
|
矿物岩石地球化学通报
,2015,34(6):1231-1237 【核心库】
|
DOI
|
10.3969/j.issn.l007-2802.2015.06.015
|
关键词
|
页岩
;
微量元素
;
五峰组
;
龙马溪组
;
渝东
|
地址
|
中国科学院广州地球化学研究所, 有机地球化学国家重点实验室, 广州, 510640
|
语种
|
中文 |
文献类型
|
研究性论文 |
ISSN
|
1007-2802 |
学科
|
地质学 |
基金
|
中国科学院战略性先导科技专项
|
文献收藏号
|
CSCD:5618073
|
参考文献 共
31
共2页
|
1.
Bostrom K. Genesis of ferromanganese deposits-diagnostic criteria for recent and old deposits.
Hydrothermal Process at Seafloors Spring Centers,1983:473-489
|
CSCD被引
13
次
|
|
|
|
2.
Bowker K A. Barnett shale gas production,Fort Worth Basin: Issues and discussion.
AAPG Bulletin,2007,91(4):523-533
|
CSCD被引
449
次
|
|
|
|
3.
Chalmers G R L. Geological controls on matrix permeability of Devonian Gas Shales in the Horn River and Liard basins,northeastern British Columbia,Canada.
International Journal of Coal Geology,2012,103:120-131
|
CSCD被引
33
次
|
|
|
|
4.
Convey R M Jr. Ni-Mo-PGE-Au-rich ores in Chinese black shales and speculations on possible analogues in the United States.
Mineralium Deposita,1991,26(2):83-88
|
CSCD被引
41
次
|
|
|
|
5.
Convey R M Jr. Gold and platinum in shales with evidence against extraterrestrial sources of metals.
Chemical Geology,1992,99(1/3):101-114
|
CSCD被引
29
次
|
|
|
|
6.
Cronan D S. Underwater minerals. London: Academic press Fan D L,Yang R Y,Huang Z X. 1984. The Lower Cambrian black shale series and the iridium anomaly in south China.
Development in Geosciences-Contributions to the 27th International Geological Congress,1980:215-224
|
CSCD被引
1
次
|
|
|
|
7.
Gromet L P. The"North American shale composite": Its compilation, major and trace element characteristics.
Geochimica et Cosmochimica Acta,1984,48(12):2469-2482
|
CSCD被引
249
次
|
|
|
|
8.
Jones B. Comparison of geochemical indices used for the interpretation of palaeoredox conditions in ancient mudstones.
Chemical Geology,1994,111(1/4):111-129
|
CSCD被引
721
次
|
|
|
|
9.
Li S R. Source tracing of noble metal elements in Lower Cambrian black rock series of Guizhou-Hunan Provinces,China.
Science in China(Series D),2000,2000,43(6):625-632
|
CSCD被引
12
次
|
|
|
|
10.
Lott D A. Sedimentary exhalative nickel-molybdenum ores in South China.
Economic Geology,1999,94(7):1051-1066
|
CSCD被引
38
次
|
|
|
|
11.
Mao J W. Re-Os dating of polymetallic Ni-Mo-PGE-Au mineralization in Lower Cambrian black shales of South China and its geologic significance.
Economic Geology,2002,97(5):1051-1061
|
CSCD被引
111
次
|
|
|
|
12.
Mills R A. Rare Earth element geochemistry of hydrothermal deposits from the active TAG Mount,26°N Mid-Atlantic Ridge.
Geochemica et Cosmochimica Acta,1995,59(17):3511-3524
|
CSCD被引
114
次
|
|
|
|
13.
Montgomery S L. Mississippian Barnett Shale,Fort Worth basin,north-central Texas: Gasshale play with multi-trillion cubic foot potential.
AAPG Bulletin,2005,89(2):155-175
|
CSCD被引
289
次
|
|
|
|
14.
Raiswell R. Degree of pyritization of iron as a paleoenvironmental indicator of bottom-water oxygenation.
Journal of Sedimentary Petrology,1988,58(5):812-819
|
CSCD被引
46
次
|
|
|
|
15.
Rimmer S M. Geochemical paleoredox indicators in Devonian-Mississippian black shales, Central Appalachian Basin (USA).
Chemical Geology,2004,206(3/4):373-391
|
CSCD被引
192
次
|
|
|
|
16.
Rona P A. Criteria for recognition of hydrothermal mineral deposits in oceanic crust.
Economic Geology,1978,73(2):135-160
|
CSCD被引
76
次
|
|
|
|
17.
Steiner M. Submarine-hydrothermal exhalative ore layers in black shales from South China and associated fossils-insights into a Lower Cambrian facies and bio-evolution.
Palaeogeography,Palaeoclimatology,Palaeoecology,2001,169(3/4):165-191
|
CSCD被引
127
次
|
|
|
|
18.
Taylor S R.
The continental crust: Its composition and evolution,1985:312
|
CSCD被引
277
次
|
|
|
|
19.
Toth J R. Deposition of submarine crusts rich in manganese and iron.
Geological Society of America Bulletin,1980,91(1):44-54
|
CSCD被引
48
次
|
|
|
|
20.
Wignall P B. Oceanic anoxia and the end Permian mass extinction.
Science,1996,272(5265):1155-1158
|
CSCD被引
195
次
|
|
|
|
|