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挪威海Nyegga麻坑区的甲烷成因自生碳酸盐岩
Methane-derived authigenic carbonates in Nyegga pockmarks, offshore Mid-Norway

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冯先翠 1   王伟 2   王文倩 3   陈毅凤 1 *  
文摘 Nyegga麻坑区位于中挪威海大陆坡边缘Storegga海底滑坡的北缘,本研究的甲烷成因自生碳酸盐岩采自该麻坑区的CN03、Tobic、DoDo和G11四个麻坑内的海底面之上。碳酸盐岩孔洞和裂隙非常发育,部分碳酸盐岩胶结有大量的化学自养贝壳,表面被红褐色-黑色的铁锰氢氧化物覆盖。碳酸盐矿物以泥晶高镁方解石和针状文石为主导,伴有极少量的白云石。草莓状黄铁矿和球粒分布广泛,揭示了碳酸盐岩形成时的还原环境及形成过程中微生物的参与。碳酸盐岩的δ~(13)C_(PDB)值为-58.67‰~-47.46‰,清楚地表明这些甲烷成因自生碳酸盐岩经甲烷厌氧氧化过程而形成,且微生物成因的甲烷为其主导碳源。碳酸盐岩的δ~(13)C值还有效地指示了麻坑间沉积物甲烷的δ~(13)C值的差异。
其他语种文摘 Nyegga pockmark field is located at the northern flank of the Storegga Slide on the mid-Norwegian margin. The carbonate samples were collected on the seafloor inside the pockmarks CN03,Tobic, DoDo and G11. The carbonates are characteristic of a high abundance of various voids and fissures, and are covered by a thin black or red-brown coating of Mn/Fe hydroxides. Samples from Pockmark Tobic are cemented with numerous chemosynthetic bivalves. The carbonate minerals are predominated by micritic high-magnesian calcite and acicular aragonite, with little dolomite. Peloids and framboidal pyrites are abundant, indicating the reducing conditions and microbial-mediated processes during precipitation of the carbonates. The δ~(13)C_(PDB) values range from -58.67 to -47.46‰,clearly demonstrating that the carbonates are cold-seep carbonates derived from the processes of anaerobic methane oxidation coupling with sulfate reduction, and microbial methane is the dominant carbon source. Meanwhile δ~(13)C values of the carbonates effectively reflect the difference in δ~(13)C values of methane in the correspondent pockmarks.
来源 地球化学 ,2015,44(4):348-359 【核心库】
关键词 Nyegga麻坑区 ; 甲烷成因自生碳酸盐岩 ; 岩石学和矿物学 ; δ~(13)C值
地址

1. 中国科学院广州地球化学研究所, 中国科学院边缘海地质重点实验室, 广东, 广州, 510640  

2. 中国科学院南京地质古生物研究所, 江苏, 南京, 210008  

3. 中国科学院大学, 北京, 100049

语种 中文
文献类型 研究性论文
ISSN 0379-1726
学科 地质学;海洋学
基金 国家自然科学基金 ;  留学回国人员科研启动基金第43批
文献收藏号 CSCD:5471293

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引证文献 3

1 刘兴健 南海白云凹陷东侧巨型麻坑中自生碳酸盐岩的特征及其地质意义 海洋地质与第四纪地质,2017,37(6):119-127
CSCD被引 4

2 肖恩照 微生物白云岩形成机制研究进展与存在问题 大庆石油地质与开发,2017,36(2):26-32
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