Speciation evolutions of target metals (Cd, Pb) influenced by chlorine and sulfur during sewage sludge incineration
查看参考文献23篇
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文摘
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In sludge incineration, the thermal behavior of heavy metal is a growing concern. In this work, the combined analysis of metal partitioning behavior between vapor phase and condensed phase, speciation redistribution in condensed phase and the difference of metal species in binding energy was carried out to investigate the possible volatilization-condensation mechanism of heavy metals in high-temperature sludge incineration. It was found that there were two steps in metal volatilization. The initial volatilization of heavy metal originated from their exchangeable (EXC), carbonate bound (CAR) and iron– manganese bound (FM) fractions, which is primarily composed of simple substance, chlorides, oxides and sulfides. With the increase of chlorine and sulfur in sludge, the inner speciation redistribution of heavy metals occurred in condensed phase, which was an important factor affecting the potential volatility of heavy metals. A partial of metal species with complexed (COM) and residual (RES) fractions gradually decomposed into simple substance or ions, oxides and carbonates, which significantly strengthened the second volatility. In presence of chlorine, about 46% of Cd with the RES fraction disappeared when the volatility rate of Cd increased by 44.89%. Moreover, about 9% of Pb with COM fraction disappeared when there was an increase of nearly 10% in the volatilization rate. Thus, the second volatilization was mainly controlled by the decomposition of metal species with COM and RES fractions. By virtue of XRD analysis and the binding energy calculation, it was found that metal complex and silicates were inclined to decompose under high temperature due to poor thermo stability as compared with sulfates. |
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来源
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Frontiers of Environmental Science & Engineering
,2014,8(6):871-876 【核心库】
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DOI
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10.1007/s11783-013-0621-1
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关键词
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sludge incineration
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heavy metals
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inner speciation redistribution
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binding energy
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地址
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College of Energy and Environment, Shenyang Aerospace University, Key Laboratory of Clean Energy (Liaoning Province), Shenyang, 110136
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语种
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英文 |
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文献类型
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研究性论文 |
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ISSN
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2095-2201 |
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基金
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国家973计划
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国家自然科学基金
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文献收藏号
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CSCD:5325421
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参考文献 共
23
共2页
|
|
1.
Marani D. Behaviour of Cd, Cr, Mn, Ni, Pb, and Zn in sewage sludge incineration by fluidised bed furnace.
Waste Management (New York, N.Y.),2003,23(2):117-124
|
CSCD被引
1
次
|
|
|
|
|
2.
Zhang H. Fate of heavy metals during municipal solid waste incineration in Shanghai.
Journal of Hazardous Materials,2008,156(1/3):365-373
|
CSCD被引
36
次
|
|
|
|
|
3.
Murakami T. Combustion characteristics of sewage sludge in an incineration plant for energy recovery.
Fuel Processing Technology,2009,90(6):778-783
|
CSCD被引
36
次
|
|
|
|
|
4.
Yao J. Content, mobility and transfer behavior of heavy metals in MSWI bottom ash in Zhejiang Province, China.
Fuel,2010,89(3):616-622
|
CSCD被引
9
次
|
|
|
|
|
5.
Zhang Y. Experimental and thermodynamic investigation on transfer of cadmium influenced by sulfur and chlorine during municipal solid waste (MSW) incineration.
Journal of Hazardous Materials,2008,153(1/2):309-319
|
CSCD被引
27
次
|
|
|
|
|
6.
Rio S. Heavy metal vaporization and abatement during thermal treatment of modified wastes.
Journal of Hazardous Materials,2007,148(3):521-528
|
CSCD被引
10
次
|
|
|
|
|
7.
Amand L E. Metal emissions from co-combustion of sewage sludge and coal/wood in fluidized bed.
Fuel,2004,83(13):1803-1821
|
CSCD被引
13
次
|
|
|
|
|
8.
Zorpas A A. Impact of thermal treatment on metal in sewage sludge from the Psittalias Wastewater Treatment Plant, Athens, Greece.
Journal of Hazardous Materials,2001,82(3):291-298
|
CSCD被引
14
次
|
|
|
|
|
9.
Mkilaha I S N. Thermodynamic analysis of the role of chlorine and sulfur environments during combustion and incineration processes.
Journal of Material Cycles and Waste Management,2002,4(2):143-149
|
CSCD被引
1
次
|
|
|
|
|
10.
Belevi H. Factors determining the element behavior in municipal solid waste incinerators. 1. Field studies.
Environmental Science and Technology,2000,34(12):2501-2506
|
CSCD被引
50
次
|
|
|
|
|
11.
Wang K S. Effects of chlorides on emissions of toxic compounds in waste incineration: study on partitioning characteristics of heavy metal.
Chemosphere,1999,38(8):1833-1849
|
CSCD被引
40
次
|
|
|
|
|
12.
Belevi H. Factors determining the element behavior in municipal solid waste incinerators. 2. Laboratory experiments.
Environmental Science and Technology,2000,34(12):2507-2512
|
CSCD被引
23
次
|
|
|
|
|
13.
Toledo J M. The partitioning of heavy metals in incineration of sludges and waste in a bubbling fluidized bed 2. Interpretation of results with a conceptual model.
Journal of Hazardous Materials,2005,126(1/3):158-168
|
CSCD被引
8
次
|
|
|
|
|
14.
Pedersen A J. Release to the gas phase of metals, S and Cl during combustion of dedicated waste fractions.
Fuel Processing Technology,2010,91(9):1062-1072
|
CSCD被引
3
次
|
|
|
|
|
15.
Jung C H. Metal distribution in incineration residues of municipal solid waste (MSW) in Japan.
Waste Management (New York, N.Y.), PMID:15081066,2004,24(4):381-391
|
CSCD被引
13
次
|
|
|
|
|
16.
Chen J C. Two-stage simulation of the major heavy-metal species under various incineration conditions.
Environment International,1998,24(4):451-466
|
CSCD被引
1
次
|
|
|
|
|
17.
Van de Velden M. The distribution of heavy metals during fluidized bed combustion of sludge (FBSC).
Journal of Hazardous Materials,2008,151(1):96-102
|
CSCD被引
12
次
|
|
|
|
|
18.
Elled A L. The fate of trace elements in fluidised bed combustion of sewage sludge and wood.
Fuel,2007,86(5/6):843-852
|
CSCD被引
6
次
|
|
|
|
|
19.
Liu Z. Speciation evolutions of heavy metals during the sewage sludge incineration in a laboratory scale incinerator.
Energy and Fuels,2010,24(4):2470-2478
|
CSCD被引
5
次
|
|
|
|
|
20.
Diaz-Somoano M. Prediction of trace element volatility during co-combustion processes.
Fuel,2006,85(7/8):1087-1093
|
CSCD被引
3
次
|
|
|
|
|
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