N-溴代丁二酰亚胺水相氧化醇类化合物反应研究
Oxidation of Alcohols by N-bromosuccinimide in Water
查看参考文献22篇
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文摘
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以水为反应介质、NBS为氧化剂,在水相无催化剂条件下实现了醇的氧化.芳香醇、脂肪醇都可以达到95%以上的醛(或酮)产率,但该体系对一些含供电子取代基的醇的反应活性不高,选用salen-Co(Ⅲ)配合物作为催化剂,可拓宽反应的底物适用范围. |
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其他语种文摘
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The oxidation of alcohols by N-bromosuccinimide with water as the reaction medium was developed.A series of alcohols including benzylic and aliphatic alcohols were converted into the corresponding ketones or aldehydes in high yields under catalyst-free conditions in water,except for some alcohols bearing donating substituents.However,the oxidation of less active alcohols could be carried out smoothly with Salen-Co(III) complex as a catalyst in a medium of water and CH2Cl2 mixture. |
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来源
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分子催化
,2012,26(2):99-104 【核心库】
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关键词
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N-溴代丁二酰亚胺
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氧化
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醇
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水
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salen-Co(Ⅲ)配合物
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地址
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中国科学院兰州化学物理研究所, 羰基合成与选择氧化国家重点实验室, 甘肃, 兰州, 730000
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语种
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中文 |
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文献类型
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研究性论文 |
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ISSN
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1001-3555 |
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学科
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化学 |
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基金
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国家自然科学基金青年科学基金资助项目
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文献收藏号
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CSCD:4513451
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参考文献 共
22
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