铜在水蒸气相中溶解的初步实验
A Preliminary Study of the Solubility of Copper in Water Vapor
查看参考文献21篇
|
文摘
|
近年来地质证据和少量的实验研究证实,相当量的铜可以在气相中迁移,人们认识到铜在气相中迁移是一种重要的地球化学过程,但目前关于铜在气相中溶解反应机理的研究还相当缺乏.本文通过溶解度法,在310～350℃,压力为4.2～10 MPa的条件范围内,实验研究了铜在不饱和水蒸气相中的溶解度.结果表明：水蒸气的存在大大增强了铜在气相中的溶解度;恒定温度下,铜在气相中的溶解度随着水蒸气压的增加而增大;气相中铜可能以水合物的形式存在,铜在气相中的溶解可由以下反应表述：CuClm^solid ＋nH2O^gas=CuClm·（H2O）n^gas（m=1,2）,其中水合数随着温度升高而下降,温度为310℃水合数n为～6,330℃为～5,350℃为～4.研究结果明确显示,气体溶剂H2O与铜之间的反应可大大增强铜在气相中的溶解和迁移能力. |
|
其他语种文摘
|
In recent years, geological evidence and the available experimental data have shown that a significant quantity of copper can be transported in vapor. It has been recognized that the transport of copper in vapor may be an important geochemical process. But, up to now, little work has been done on the mechanisms of dissolution of copper in vapor. In this paper, the solubility of copper in undersaturated water vapor was investigated experimentally at temperatures of 310 to 350℃and pressures from 4. 2 to 10 MPa. Results of these experiments show that the presence of water vapor increases the concentration of Cu in the gas. At the same temperature, the solubility of copper increases with the increase of water vapor pressure. Copper may exist as hydrated gaseous particles in the vapor phase. The dissolution process can be described by the reaction：CuClm^solid ＋nH2O^gas=CuClm·（H2O）n^gas（m=1,2）. The hydration number decreases with increasing temperature, varying from -6 at 310 ℃, to -5 at 330 ℃ and -4 at 350℃. The results show that the interactions between gas-solvent H2O and copper significantly enhance the capacity of dissolution and transport of copper in the gas phase. |
|
来源
|
地球科学
,2006,31(3):321-325 【核心库】
|
|
关键词
|
铜
;
气相
;
溶解度
;
实验研究
|
|
地址
|
中国科学院地球化学研究所, 中科院矿床地球化学重点实验室, 贵州, 贵阳, 550002
|
|
语种
|
中文 |
|
文献类型
|
研究性论文 |
|
ISSN
|
1000-2383 |
|
学科
|
地质学 |
|
基金
|
中国科学院知识创新工程重要方向项目
;
国家自然科学基金项目
;
中国科学院西部之光人才培养计划
|
|
文献收藏号
|
CSCD:2450551
|
参考文献 共
21
共2页
|
|
1.
Archibald S M. The stability of Au-chloride complexes in water vapor at elevated temperatures and pressures.
Geochimica et Cosmochimica Acta,2001,65(23):4413-4423
|
CSCD被引
27
次
|
|
|
|
|
2.
Archibald S M. An experimental study of the stability of copper chloride complexes in water vapor at elevated temperatures and pressures.
Geochimica et Cosmochimica Acta,2002,66(9):1611-1619
|
CSCD被引
27
次
|
|
|
|
|
3.
Barnes H L.
Geochemistry of hydrothermal ore deposits. 3rd edition,1997
|
CSCD被引
3
次
|
|
|
|
|
4.
Brewer L. The thermodynamics of gaseous cuprous chloride.
J.Am.Chem.Soc,1950,72:3038-3045
|
CSCD被引
1
次
|
|
|
|
|
5.
Dienstbach F. Vaporization of copper(Ⅱ)chloride and the structure of vapor studied using UV/visible and Raman spectroscopy.
Inst.Anorg.Anal.Chem.Helv.Chim.Acta,1977,60:2460-2470
|
CSCD被引
1
次
|
|
|
|
|
6.
Gemmell J B. Geochemistry of metallic trace elements in fumarole condenstates from Nicaraguan and Costa Rican volcanoes.
Journal of Volcanology and Geothermal Research,1987,33:161-181
|
CSCD被引
10
次
|
|
|
|
|
7.
Heinrich C H. Segregation of ore metals between magmatic brine and vapor:A fluid inclusion study using PIXE microanalysis.
Economic Geology,1992,87:1566-1583
|
CSCD被引
60
次
|
|
|
|
|
8.
Heinrich C A.
Geology,1999,87:755-758
|
CSCD被引
101
次
|
|
|
|
|
9.
Kestin J. Thermophysical properties of fluid H2 O.
J.Phys.Chem.Ref.Data,1984,13:175-183
|
CSCD被引
5
次
|
|
|
|
|
10.
Lowenstern J B. Evidence for extreme partitioning of copper into a magmatic vapor phase.
Science,1991,252(7):1405-1409
|
CSCD被引
33
次
|
|
|
|
|
11.
Migdisov A A. Solubility of chlorargyrite(AgCl)in the water vapor at elevated temperature and pressures.
Geochimica et Cosmochimica Acta,1999,63(22):3817-3827
|
CSCD被引
22
次
|
|
|
|
|
12.
Peterson D E.
Sublimation thermodynamics and kinetics of cuprous-chloride.Part Ⅰ:Vacuum balancetorsion experiments.Part Ⅱ:Mass-spectrometer experiments (Dissertation),1973:484
|
CSCD被引
1
次
|
|
|
|
|
13.
Pokrovski G B. Experimental study of arsenic speciation in vapor phase to 500℃:Implications for As transport and fractionation in low-density crustal fluids and volcanic gases.
Geochimica et Cosmochimica Acta,2002,66(19):3453-3480
|
CSCD被引
1
次
|
|
|
|
|
14.
Seward T M. An X-ray absorption(EXAFS)spectroscopic study of aquated Ag+in hydrothermal solutions to 350℃.
Geochim.Cosmochim.Acta,1996,60:2273-2282
|
CSCD被引
2
次
|
|
|
|
|
15.
Sheller B.
A transpiration-mass spectrometric technique for the determination of the thermodynamic properties of chloride vapor transport reactions(Dissertation),1976:197
|
CSCD被引
1
次
|
|
|
|
|
16.
Taran Y A. Native gold in mineral precipitates from high temperature volcanic gases of Colima volcano.
Applied Geochemistry,2000,15:337-346
|
CSCD被引
22
次
|
|
|
|
|
17.
Ulrich T.
Nature,1999,399(17):676-679
|
CSCD被引
132
次
|
|
|
|
|
18.
Williams-Jones A E. Vapor-transport of ore metals.
Water-Rock Interactions,Ore Deposits,and Envrionmental Geochemistry,2002,7:279-305
|
CSCD被引
1
次
|
|
|
|
|
19.
Xiao Z.
Experimental and theoretical studies of the solubility of copper in liquid and vapor in the system NaCl-HCl-H2O(Dissertation),1999
|
CSCD被引
1
次
|
|
|
|
|
20.
Zakaznova-Iakovleva V P. An experimental study of stibnite solubility in gaesous hydrogen sulphside from 200 to 320℃.
Geochimica et Cosmochimica Acta,2001,65(2):289-298
|
CSCD被引
5
次
|
|
|
|
|
了解气象卫星更多信息，请访问