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土壤和沉积物中重金属积累及其Pb、S同位素示踪
ACCUMULATION OF HEAVY METALS IN SOILS AND SEDIMENTS AND DETERMINATION OF POLLUTANT SOURCE BY Pb AND S ISOTOPIC TRACERS

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文摘 对榨子厂附近一个废弃多年的古老土法炼锌点土壤和沉积物中重金属的积累及污染程度进行了研究.研究区土壤、沉积物样品中Pb、Zn、Cd含量已大大高于该地区的背景值,Zn的积累明显大于Pb的积累程度.相关分析表明,土壤和沉积物中FezO3对重金属有强烈的固定作用.沉积物和土壤中有很高的综合污染指数,显示出重金属的污染程度很高.化学形态分析表明重金属以碳酸盐结合态、残渣态和铁锰氧化物结合态为主,有效态所占的比例很低,但其含量并不很低,在酸性条件下,有释放导致污染的可能性.同位素示踪结果显示,研究区土壤和沉积物中积累的Pb、S为矿山物质来源.
其他语种文摘 In the study region, heavy metals in soils and sediments, as observed, greatly exceed the regional background values. Cor-relation analyses revealed high positive correlations between Fe..O,, and heavy metal concentrations, indicating stronger abilities of Fe2O3 to fix heavy metals. Very high CPI values could be figured out for heavy metals in soils and sediments, showing a very high pollution degree of heavy metals. Results of sequential extraction demonstrated that heavy metals were bound mainly to carbonate, iron and manganese oxides, and minerals; only a few exchangeable fractions were extracted. But exchangeable frac-tion metals are high in concentrations, indicating a pollution possibility by heavy metal released under acidic conditions. Pb and S isotopic tracers gave results that heavy metals accumulated in soils and sediments were mainly from mine substances, espe-cially those from local Zn smelting in the region.
来源 地球与环境 ,2004,32(1):76-81 【核心库】
关键词 重金属 ; 综合污染指数 ; 化学形态 ; 同位素示踪
地址

中国科学院地球化学研究所, 贵州, 贵阳, 550002

语种 中文
文献类型 研究性论文
ISSN 1672-9250
学科 环境质量评价与环境监测
基金 中国科学院知识创新工程项目
文献收藏号 CSCD:1673323

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引证文献 9

1 刘敬勇 元素-铅同位素示踪在云浮硫铁矿区土壤铊污染研究中的应用 物探与化探,2006,30(4):348-353
CSCD被引 11

2 邵学新 土壤重金属污染来源及其解析研究进展 广东微量元素科学,2007,14(4):1-6
CSCD被引 32

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